Chen Ze, Cui Bing, Guo Xiaohan, Zhou Bin, Wang Shishuai, Pei Yaqiong, Li Bin, Liang Hongshan
College of Food Science and Technology, Huazhong Agricultural University, Wuhan, China.
Key Laboratory of Environment Correlative Dietology, Ministry of Education, Huazhong Agricultural University, Wuhan, China.
J Sci Food Agric. 2022 Feb;102(3):949-956. doi: 10.1002/jsfa.11427. Epub 2021 Aug 28.
The waste of salted egg white resources has always been a serious problem in the food industry. In this current study, we report on a kind of Pickering emulsion system, which was stabilized by duck egg white nanogels (DEWNs) and sodium alginate (SA), followed by which this system was crosslinked by calcium carbonate (CaCO ) via controlling the gluconolactone (GDL) concentrations, aiming to open up a promising route for making full use of these protein resources.
The droplet size of the emulsion exhibited a reduction with an increase in SA concentrations, indicating that higher negative charges and steric hindrance was useful for a stable emulsion system. Meanwhile, the result of rheology measurement showed that storage modulus (G') values were higher than loss modulus (G″) values of the samples at higher GDL concentration, revealing the formation of elastic gel-like networks in the system, which was fabricated by SA and Ca released by the CaCO particles. The gel-like network structure in the continuous phase improved both the freeze-thaw and thermal stability of the obtained Pickering emulsion system. Encouragingly, the Pickering high internal phase emulsions (HIPEs, φ = 0.75) stabilized by DEWN/SA -GDL were prepared, which could be stored at 4 °C for at least 30 days without oiling-off and creaming.
These findings not only develop a green ultra-stable Pickering emulsion system but also extend the potential commercial applications of duck egg white proteins in the food, cosmetics, and pharmaceutical industries. © 2021 Society of Chemical Industry.
咸蛋白资源的浪费一直是食品工业中的一个严重问题。在本研究中,我们报道了一种皮克林乳液体系,该体系由鸭蛋清纳米凝胶(DEWNs)和海藻酸钠(SA)稳定,随后通过控制葡萄糖酸内酯(GDL)浓度使该体系由碳酸钙(CaCO₃)交联,旨在为充分利用这些蛋白质资源开辟一条有前景的途径。
乳液的液滴尺寸随SA浓度的增加而减小,表明较高的负电荷和空间位阻有利于形成稳定的乳液体系。同时,流变学测量结果表明,在较高GDL浓度下,样品的储能模量(G')值高于损耗模量(G'')值,这表明体系中形成了弹性凝胶状网络,该网络由CaCO₃颗粒释放的SA和Ca构成。连续相中的凝胶状网络结构提高了所得皮克林乳液体系的冻融稳定性和热稳定性。令人鼓舞的是,制备了由DEWN/SA -GDL稳定的皮克林高内相乳液(HIPEs,φ = 0.75),其可在4℃下储存至少30天而不发生油析和分层。
这些发现不仅开发了一种绿色超稳定的皮克林乳液体系,还拓展了鸭蛋清蛋白在食品、化妆品和制药行业的潜在商业应用。© 2021化学工业协会。