共轭双芳基乙烯基底物的合成及其向菲衍生物的光电子环化反应。
The Synthesis of Conjugated Bis-Aryl Vinyl Substrates and Their Photoelectrocyclization Reactions towards Phenanthrene Derivatives.
作者信息
Zhao Xuchen, Rainier Jon D
机构信息
Department of Chemistry, University of Utah, 315 E. 1400 S., Salt Lake City, Utah 84108, USA.
出版信息
Synthesis (Stuttg). 2021;53(7):1200-1212. doi: 10.1055/s-0040-1706001. Epub 2021 Jan 11.
Abstract
The photoelectrocyclization of conjugated vinyl biaryls has proven to be a valuable and efficient strategy for generating phenanthrene derivatives. Contained in this review is an overview of the mechanism for the transformation and a discussion of the reaction scope with a focus on the electrocyclization itself, rearomatization, and the application of the reaction in natural product synthesis.
摘要
共轭乙烯基联芳基的光致电环化反应已被证明是生成菲衍生物的一种有价值且高效的策略。本综述包含了该转化反应机理的概述，以及对反应范围的讨论，重点在于电环化反应本身、再芳构化反应，以及该反应在天然产物合成中的应用。
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