具有两性离子基态的氮掺杂不对称并苯烯基。
A nitrogen-doped asymmetric phenalenyl with a zwitterionic ground state.
作者信息
Miao Fang, Chen Hanjiao, Moles Quintero Sergio, Xue Guodong, Casado Juan, Zheng Yonghao
机构信息
School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China (UESTC), Chengdu 611731, P. R. China.
出版信息
Chem Commun (Camb). 2021 Sep 4;57(68):8433-8436. doi: 10.1039/d1cc02890a. Epub 2021 Aug 2.
Herein, an asymmetric N-doped phenalenyl (BTAP) compound has been synthesized and carefully studied for the first time. The synthesis of BTAP reveals a planar configuration and an unexpected zwitterionic ground state with the negative charge delocalized around the circumjacent part and the positive charge mainly localized on the center.
在此，首次合成并仔细研究了一种不对称的氮掺杂苊烯基（BTAP）化合物。BTAP的合成揭示了一种平面构型以及一种意想不到的两性离子基态，其中负电荷围绕周边部分离域，正电荷主要定域在中心。
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