Rangraz Yalda, Heravi Majid M, Elhampour Ali
Department of Chemistry, School of Physics and Chemistry, Alzahra University, PO Box 19938-93973, Vanak, Tehran, Iran.
Department of Chemistry, Semnan University, PO Box 35131-19111, Semnan, Iran.
Chem Rec. 2021 Aug;21(8):1985-2073. doi: 10.1002/tcr.202100124. Epub 2021 Jul 1.
Design and preparation of low-cost, effective, and novel catalysts are important topics in the field of heterogeneous catalysis from academic and industrial perspectives. Recently, heteroatom-doped porous carbon/metal materials have received significant attention as promising catalysts in divergent organic reactions. Incorporation of heteroatom into the carbon framework can tailor the properties of carbon, providing suitable interaction between support and metal, resulting in superior catalytic performance compared with those of traditional pure carbon/metal catalytic systems. In this review, we try to underscore the recent advances in the design, preparation, and application of heteroatom-doped porous carbon/metal catalysts towards various organic transformations.
从学术和工业角度来看,设计和制备低成本、高效且新颖的催化剂是多相催化领域的重要课题。近年来,杂原子掺杂的多孔碳/金属材料作为多种有机反应中颇具潜力的催化剂受到了广泛关注。将杂原子引入碳骨架可以调整碳的性质,在载体与金属之间提供合适的相互作用,与传统的纯碳/金属催化体系相比,从而产生优异的催化性能。在这篇综述中,我们试图强调杂原子掺杂的多孔碳/金属催化剂在各种有机转化反应的设计、制备及应用方面的最新进展。