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外加电场促进废水中氨的汽提。

External electric field promotes ammonia stripping from wastewater.

机构信息

Department of Environmental Engineering, Korea Maritime and Ocean University, Busan 49112, South Korea; Interdisciplinary Major of Ocean Renewable Energy Engineering, Korea Maritime and Ocean University, Busan 49112, South Korea.

Nuclear Power Equipment Research Center, Korea Maritime and Ocean University, Busan 49112, Korea.

出版信息

Water Res. 2021 Sep 15;203:117518. doi: 10.1016/j.watres.2021.117518. Epub 2021 Aug 5.

Abstract

The gas stripping process is widely used for the removal and recovery of ammonia from wastewater. The ammonia removal in the stripping process depends on the pH, temperature, and air supply, and in general, 10.5, 60 °C, 5 L/min or more are recommended as near-optimal. However, alkaline chemicals and energy can seriously burden the stripping process operation, depending on the wastewater characteristics. Herein, external electric field-coupled ammonia stripping, which improves ammonia removal from aqueous solutions, was investigated. The ammonia removal in the conventional stripping was between 17.7 % and 90.6 %, depending on how close to the near-optimal conditions. The electric field increased the removal efficiency from 51.1 % to 94.3 %, as the strength and frequency increased to 15 V/cm and 50 MHz. The electric field promotion of ammonia stripping correlated closely with the increase in ammonia molecular diffusion. The electric field has been shown to improve the diffusion of ammonia molecules without dielectric heating by increasing the kinetic energy. The electric field improved the ammonia removal more as the pH, temperature, and air supply conditions were far from optimal. The electric field reduces the alkaline chemicals and the electric energy for heating and air supply, and the energy consumption to form the electric field is only a few watts. The electric field-coupled process offers a new gas stripping platform that can economically improve ammonia removal from wastewater.

摘要

汽提工艺广泛用于从废水中去除和回收氨。汽提过程中的氨去除取决于 pH 值、温度和供气,通常建议接近最佳条件为 10.5、60°C 和 5 L/min 或更高。然而,根据废水的特性,碱性化学品和能源会严重影响汽提过程的运行。在此,研究了外部电场耦合汽提,该方法可提高水溶液中氨的去除率。在常规汽提中,氨的去除率在 17.7%至 90.6%之间,具体取决于接近最佳条件的程度。随着强度和频率增加到 15 V/cm 和 50 MHz,电场将去除效率从 51.1%提高到 94.3%。电场促进氨汽提与氨分子扩散的增加密切相关。电场通过增加动能来改善氨分子的扩散,而无需介电加热。当 pH 值、温度和供气条件远离最佳条件时,电场对氨去除的改善效果更大。电场减少了用于加热和供气的碱性化学品和电能,形成电场的能耗仅为几瓦。电场耦合工艺提供了一个新的气体汽提平台,可以经济地提高废水中氨的去除率。

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