Department of Environmental Studies, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara, 390 002, India.
Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara, 390 002, India.
Environ Sci Pollut Res Int. 2022 Jan;29(1):236-250. doi: 10.1007/s11356-021-15887-y. Epub 2021 Aug 21.
Modern lifestyle and alleviated anthropogenic activities have increased the pollutant load, ultimately causing stress on the environment. In industrialization, many harmful compounds are released into the environment polluting air, water, and soil, triggering adverse impacts on the ecosystem and human beings. Therefore, the development of advanced remediation technologies turns out as a significant environmental priority. Less polar cyclic oligosaccharide Cyclodextrin (CD) with cavity binding organic compounds attracted attention by helping effectively as environmental application. The formation of inclusion complexes and modified Cyclodextrin by cross-linking or surface modification enhances their capacity to abate pollutant effectively from the environment. Modification results in the formation of several novel materials such as CD-based composites, nanocomposites, crosslinked polymer or hydrogels, potent cross-linkers, CD-based membranes, and CD immobilized supports. Several environmental remediation technologies based on Cyclodextrin and modified Cyclodextrin have been discussed in detail in this review. Various environmental applications of Cyclodextrin and its derivatives have been discussed, along with their formation, properties, and characterization. Effective removal of organic pollutants, inorganic pollutants, micropollutants, volatile compounds etc., has been explained using several remediation technologies. Based on CD innocuity, this is referred to as the green process. The reversible equilibrium corresponded by the inclusion phenomenon sets a significant trend in the field of CD environmental application to develop techniques by incorporating supramolecular chemistry as well as irreversible methods such as biodegradation and advanced oxidation. It helps in the complete removal of pollutants and ultimately recycling the CD.
现代生活方式和减轻的人为活动增加了污染物负荷,最终对环境造成压力。在工业化过程中,许多有害化合物被释放到环境中,污染空气、水和土壤,对生态系统和人类产生不利影响。因此,开发先进的修复技术成为一个重要的环境优先事项。具有较小极性的环状低聚糖环糊精 (CD) 因其能有效地作为环境应用而吸引了人们的注意。通过交联或表面修饰形成包合物和改性 CD,可增强其从环境中有效去除污染物的能力。改性会形成几种新型材料,如基于 CD 的复合材料、纳米复合材料、交联聚合物或水凝胶、有效交联剂、基于 CD 的膜和固定化 CD 的载体。本文详细讨论了几种基于 CD 和改性 CD 的环境修复技术。讨论了 CD 及其衍生物的各种环境应用,以及它们的形成、性质和特性。使用几种修复技术解释了对有机污染物、无机污染物、微污染物、挥发性化合物等的有效去除。基于 CD 的无害性,这被称为绿色工艺。包合现象所对应的可逆平衡为 CD 环境应用领域的发展趋势设定了重要方向,即将超分子化学以及生物降解和高级氧化等不可逆方法结合起来开发技术。它有助于完全去除污染物,最终回收 CD。