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羧甲基纤维素钠(CMC-Na)和果胶的热分析研究

[Thermoanalytical studies of sodium salt of carboxymethylcellulose (CMC-Na) and pectin].

作者信息

Boussabir A, Górecki M

机构信息

Katedra Chemii Nieorganicznej i Analitycznej, Akademii Medycznej im. K. Marcinkowskiego w Poznaniu.

出版信息

Polim Med. 1987;17(3-4):147-52.

PMID:3452818
Abstract

The influence of physical and chemical properties of electrolytes on thermal degradation of CMC-Na and pectiny salt were studied. A differential thermal analysis showed that thermal decomposition of CMC-Na and pectin salt proceeds in three stages. The heat of conversion of the studied systems was shown to increase according to the concentration of the applied electrolytes. Significant changes in the structure of CMC-Na at pH = 3.0 were shown by IR analysis. Confirmation of transition of the above system to the acidic form were obtained by DTA and TG curves.

摘要

研究了电解质的物理和化学性质对羧甲基纤维素钠(CMC-Na)和果胶盐热降解的影响。差示热分析表明,CMC-Na和果胶盐的热分解分三个阶段进行。研究体系的转化热随所用电解质浓度的增加而增加。红外分析表明,在pH = 3.0时,CMC-Na的结构发生了显著变化。通过差示热分析(DTA)曲线和热重分析(TG)曲线证实了上述体系向酸性形式的转变。

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