The adsorption and dissociation of ethanol on Pt/β-MoC with a low noble metal loading (0.1 wt%) is studied in the context of catalytic H production from alcohols. X-ray diffraction and experimental results indicate that Pt modifies the lattice parameters of β-MoC. In line with this, density functional theory calculations indicate that the Mo-Mo distances are increased due to the presence of Pt. An experimental X-ray photoelectron spectroscopy study indicates that the chemical state of both molybdenum and carbon in Pt/β-MoC are very different from those in the Pt-free carbide, which is also in agreement with the DFT results, which indicate that the Pt atoms generate a redistribution of charge density in their environment. Temperature programmed reaction analysis shows that at temperatures higher than 530 K, a two-fold increase in the production of H, CH and CH is observed for Pt/β-MoC as compared to β-MoC, suggesting a higher catalytic activity for the Pt-containing carbide than for the pristine catalyst. Additionally, H production from ethanol on Pt/β-MoC presents a higher activation energy (0.64 eV) than that corresponding to pristine molybdenum carbide. In agreement with this experimental result, climbing image-nudged elastic band (CI-NEB) calculations indicate that the energy barrier linked to the formation of H from ethanol increases with the presence of platinum. It is concluded that the low Pt loading notably modifies the catalytic pattern of molybdenum carbide, rendering it a highly active catalyst for ethanol decomposition.