涉及质子电子转移（PCET）的二聚六氢吡咯并[2,3-]吲哚生物碱的氧化电有机合成：（±）-佛利坎丁的全合成。
Oxidative electro-organic synthesis of dimeric hexahydropyrrolo-[2,3-]indole alkaloids involving PCET: total synthesis of (±)-folicanthine.
机构信息
Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhauri, Bhopal - 462 066, Madhya Pradesh, India.
Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, Nadia - 741246, West Bengal, India.
出版信息
Org Biomol Chem. 2021 Nov 10;19(43):9390-9395. doi: 10.1039/d1ob01463c.
An efficient electrochemical oxidation strategy for the total synthesis of a dimeric hexahydropyrrolo[2,3-]indole alkaloid, (±)-folicanthine (1b), has been envisioned. Control experiments suggest that a PCET pathway involving stepwise electron transfer followed by proton transfer (ET-PT) was involved in the key oxidative dimerization process.
人们设想了一种高效的电化学氧化策略，用于（±）-福里坎丁（1b）这类二聚六氢吡咯并[2,3-b]吲哚类生物碱的全合成。对照实验表明，涉及逐步电子转移随后质子转移（ET-PT）的质子转移电子转移（PCET）途径参与了关键的氧化二聚化过程。
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