Key Laboratory of Regional Resource Exploitation and Medicinal Research, Faculty of Chemical Engineering, Huaiyin Institute of Technology, Huai'an, Jiangsu Province, People's Republic of China.
Institute of Chemical Sciences, University of Peshawar, Khyber Pakhtunkhwa, Peshawar, 25120, Pakistan.
Environ Sci Pollut Res Int. 2022 Jan;29(4):4822-4842. doi: 10.1007/s11356-021-17446-x. Epub 2021 Nov 17.
Metal-organic frameworks (MOFs) are a polymer hybrid family of compounds comprising metal ions that have been deliberately incorporated in organic ligands to form several multi-dimensional structures with unique structural and functional attributes. They have the typical properties of brittleness, major porosity, and randomly crystalline. These three factors hampered their potential incorporation into modern technologies. However, with the discovery of their polymers, hope was rekindled. Polymers, unlike their counterparts, are versatile and malleable and can be tailored into solids with a wide range of technical applications. MOFs can be effectively incorporated into polymer structures, resulting in polymers with enhanced properties and increased demand, according to recent studies. This review focuses on the synthetic procedures of MOFs used to create hybrid materials, as well as their potential environmentally related applications. Desalination, hazardous heavy metal removal and mitigation, gas and liquid separations and purifications, and dye removal will all be extensively discussed as applications. To assemble this review, we will add insight from recent papers and discoveries, as well as seminal reports from experts on the advancement of MOF-polymers.
金属-有机骨架(MOFs)是一种聚合物杂化家族化合物,由金属离子组成,这些金属离子已被故意纳入有机配体中,以形成具有独特结构和功能属性的几种多维结构。它们具有脆性、大孔隙率和随机结晶的典型特性。这三个因素阻碍了它们在现代技术中的潜在应用。然而,随着对其聚合物的发现,希望又重新燃起。与它们的对应物不同,聚合物具有多功能性和可延展性,可以被加工成具有广泛技术应用的固体。根据最近的研究,MOFs 可以有效地结合到聚合物结构中,从而产生具有增强性能和更高需求的聚合物。本综述重点介绍了用于制造杂化材料的 MOFs 的合成方法,以及它们在与环境相关的潜在应用。海水淡化、危险重金属去除和缓解、气体和液体分离和净化以及染料去除将作为应用广泛讨论。为了编写这篇综述,我们将从最近的论文和发现中汲取灵感,并借鉴专家关于 MOF-聚合物进展的重要报告。