Feng Pei, Shi Yuhua, Shang Peng, Wei Hanjun, Peng Tongtong, Pang Lisha, Feng Rongrong, Zhang Wenyuan
School of Equipment Management and Support, Engineering University of PAP, Xi'an 710078, China.
Science and Technology on Plasma Dynamics Lab, Air Force Engineering University, Xi'an 710038, China.
Materials (Basel). 2021 Nov 10;14(22):6781. doi: 10.3390/ma14226781.
The internal stress difference between soft-ductile aluminum alloy substrate and hard-brittle Ni-W alloy coating will cause stress concentration, thus leading to the problem of poor bonding force. Herein, this work prepared the Ni-W graded coating on aluminum alloy matrix by the pulse electrodeposition method in order to solve the mechanical mismatch problem between substrate and coatings. More importantly, a backward propagation (BP) neural network was applied to efficiently optimize the pulse electrodeposition process of Ni-W graded coating. The SEM, EDS, XRD, Vickers hardness tester and Weighing scales are used to analyze the micromorphology, chemical element, phase composition, and micro hardness as well as oxidation weight increase, respectively. The results show that the optimal process conditions with BP neural network are as follows: the bath temperature is 30 °C, current density is 15 mA/cm and duty cycle is 0.3. The predicted value of the model agrees well with the experimental value curve, the relative error is minor. The maximum error is less than 3%, and the correlation coefficient is 0.9996. The Ni-W graded coating prepared by BP neural network shows good bonding with the substrate which has flat and smooth interface. The thickness of the coating is about 136 μm, which slows down the oxidation of the substrate and plays an effective role in protecting the substrate.
软韧性铝合金基体与硬脆性Ni-W合金涂层之间的内应力差异会导致应力集中,从而引发结合力差的问题。在此,本工作通过脉冲电沉积法在铝合金基体上制备Ni-W梯度涂层,以解决基体与涂层之间的机械不匹配问题。更重要的是,应用反向传播(BP)神经网络来有效优化Ni-W梯度涂层的脉冲电沉积工艺。分别使用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、维氏硬度计和天平来分析微观形貌、化学元素、相组成、显微硬度以及氧化增重。结果表明,BP神经网络优化得到的最佳工艺条件为:镀液温度30℃,电流密度15mA/cm,占空比0.3。模型预测值与实验值曲线吻合良好,相对误差较小。最大误差小于3%,相关系数为0.9996。经BP神经网络制备的Ni-W梯度涂层与基体结合良好,界面平整光滑。涂层厚度约为136μm,减缓了基体的氧化,对基体起到了有效的保护作用。