Mohammadi Ziarani Ghodsi, Mohammadsaeed Shirin, Badiei Alireza, Ghasemi Jahan B
Department of Chemistry, Faculty of physics and chemistry, Alzahra University, P.O. Box 1993893973, Tehran, Iran.
School of Chemistry, College of Science, University of Tehran, P.O. Box, 14155-6455, Tehran, Iran.
J Fluoresc. 2022 Jan;32(1):347-357. doi: 10.1007/s10895-021-02835-9. Epub 2021 Dec 1.
A synthetic method is described to produce some chromenone-pyrazole derivatives through a one-pot multicomponent reaction using SrFeO as a magnetic catalyst. This method provides quite a few merits, including the use of an effective and easy separable nanocatalyst, high yields of products, short reaction time, and easy work-up. Two of the products showed fluorescence properties, which have detected mercury ions without any interference with other ions. They can detect a tiny amount of mercury ions, which were comparable with other chemosensors. The detection limit is 4 × 10 and 3 × 10 M, respectively, for the compound I and II, respectively, which were considered very low amounts. The effect of mercury on health and environmental pollution is essential in medical science.
描述了一种合成方法,该方法使用SrFeO作为磁性催化剂,通过一锅多组分反应制备一些色酮-吡唑衍生物。该方法具有诸多优点,包括使用有效且易于分离的纳米催化剂、产物收率高、反应时间短以及后处理简便。其中两种产物具有荧光特性,能够检测汞离子,且不受其他离子的干扰。它们能够检测微量汞离子,与其他化学传感器相当。化合物I和II的检测限分别为4×10和3×10 M,这被认为是非常低的量。汞对健康和环境污染的影响在医学领域至关重要。