Fang Neng, Zeng Lingyan, Li Zhengqi, Lu Yue, Chen Zhichao
Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing, 100190, People's Republic of China.
School of Energy Science and Engineering, Harbin Institute of Technology, Harbin, 150001, People's Republic of China.
Environ Sci Pollut Res Int. 2022 Apr;29(18):26726-26737. doi: 10.1007/s11356-021-17770-2. Epub 2021 Dec 2.
The raw syngas effluent from a fluidized bed gasifier typically contains a large amount of fly ash having a high concentration of carbon, which is undesirable. The present work examined the newly developed entrained-flow gasification technology intended to gasify raw syngas. Simulation of gas-solid flow and reaction behavior in an industrial-scale entrained-flow gasifier applying this new technology was first performed to obtain a better understanding of the particle flow and gasification characteristics. In addition, the devolatilization and heterogeneous reactions of fly ash particles were characterized by thermogravimetric analysis and user-defined function. The predictions from the simulation showed good agreement with the results of in situ experimental measurements. The combustion reaction for raw syngas occurred in the burner jet zone. As the hot gaseous products diffused, gasification reactions dominated the other zones. When burner inclination angle was 0°, 8.5°, and 25.5°, the temperature at the bottom outlet of the gasifier was lower than the ash flow temperature with the value of 1360 °C. Solid slag formed and blocked the outlet. By comparison, this gasifier with the burner inclination angle of 17° could discharge the liquid slag and function as a continuous operation. In this way, the carbon conversion in fly ash reached the maximum value of 87%.
来自流化床气化炉的粗合成气流出物通常含有大量高浓度碳的飞灰,这是不理想的。本研究考察了旨在气化粗合成气的新开发的气流床气化技术。首先对应用该新技术的工业规模气流床气化炉内气固流动和反应行为进行了模拟,以更好地了解颗粒流动和气化特性。此外,通过热重分析和用户自定义函数对飞灰颗粒的挥发分和非均相反应进行了表征。模拟预测结果与现场实验测量结果吻合良好。粗合成气的燃烧反应发生在燃烧器射流区。随着热气态产物的扩散,气化反应在其他区域占主导地位。当燃烧器倾斜角度为0°、8.5°和25.5°时,气化炉底部出口温度低于灰流温度,为1360℃。形成固体炉渣并堵塞出口。相比之下,燃烧器倾斜角度为17°的该气化炉能够排出液态炉渣并实现连续运行。这样,飞灰中的碳转化率达到了87%的最大值。