Hyder Ali, Buledi Jamil A, Nawaz Muhammad, Rajpar Dhani B, Shah Zia-Ul-Hassan, Orooji Yasin, Yola Mehmet Lütfi, Karimi-Maleh Hassan, Lin Hongjun, Solangi Amber R
National Centre of Excellence in Analytical Chemistry, University of Sindh, 76080, Jamshoro, Pakistan.
Department of Soil Science, Sindh Agriculture University, Tandojam, Pakistan.
Environ Res. 2022 Apr 1;205:112475. doi: 10.1016/j.envres.2021.112475. Epub 2021 Dec 1.
Heavy metal pollution has become a severe threat to human health and the environment for many years. Their extensive release can severely damage the environment and promote the generation of many harmful diseases of public health concerns. These toxic heavy metals can cause many health problems such as brain damage, kidney failure, immune system disorder, muscle weakness, paralysis of the limbs, cardio complaint, nervous system. For many years, researchers focus on developing specific reliable analytical methods for the determination of heavy metal ions and preventing their acute toxicity to a significant extent. The modern researchers intended to utilize efficient and discerning materials, e.g. nanomaterials, especially the metal nanoparticles to detect heavy metal ions from different real sources rapidly. The metal nanoparticles have been broadly utilized as a sensing material for the colorimetric detection of toxic metal ions. The metal nanoparticles such as Gold (Au), Silver (Ag), and Copper (Cu) exhibited localized plasmon surface resonance (LPSR) properties which adds an outstanding contribution to the colorimetric sensing field. Though, the stability of metal nanoparticles was major issue to be exploited colorimetric sensing of heavy emtal ions, but from last decade different capping and stabilizing agents such as amino acids, vitmains, acids and ploymers were used to functionalize the metal surface of metal nanoparticles. These capping agents prevent the agglomeration of nanoparticles and make them more active for prolong period of time. This review covers a comprehensive work carried out for colorimetric detection of heavy metals based on metal nanoparticles from the year 2014 to onwards.
多年来,重金属污染已对人类健康和环境构成严重威胁。它们的大量释放会严重破坏环境,并引发许多关乎公众健康的有害疾病。这些有毒重金属会导致诸多健康问题,如脑损伤、肾衰竭、免疫系统紊乱、肌肉无力、肢体麻痹、心脏病、神经系统问题等。多年来,研究人员致力于开发特定可靠的分析方法来测定重金属离子,并在很大程度上预防其急性毒性。现代研究人员打算利用高效且有识别能力的材料,例如纳米材料,尤其是金属纳米颗粒,来快速检测来自不同实际来源的重金属离子。金属纳米颗粒已被广泛用作比色检测有毒金属离子的传感材料。金(Au)、银(Ag)和铜(Cu)等金属纳米颗粒表现出局域表面等离子体共振(LPSR)特性,这对比色传感领域做出了杰出贡献。然而,金属纳米颗粒的稳定性是比色传感重金属离子时需要解决的主要问题,但在过去十年中,不同的封端和稳定剂,如氨基酸、维生素、酸和聚合物,被用于对金属纳米颗粒的金属表面进行功能化处理。这些封端剂可防止纳米颗粒团聚,并使其在较长时间内更具活性。本综述涵盖了自2014年以来基于金属纳米颗粒对比重金属进行比色检测所开展的全面工作。