Jiang Gaoqiang, Cui Chengyun, Chen Lu, Wu Yucheng, Cui Xigui
School of Mechanical Engineering, Jiangsu University, Zhenjiang 212013, China.
Materials (Basel). 2021 Dec 3;14(23):7437. doi: 10.3390/ma14237437.
To improve the wear and corrosion resistance of the pump barrel material (40Cr steel), a (M:Nb,Ta)C/Ni35 composite cladding coating by in situ synthesis of composite carbides was conducted. The effects of ceramic micro-particles content on the phase composition, microstructure of the coating, structural characteristics of (M:Nb,Ta)C and the tribology and electrochemical corrosion behavior were systematically studied. The increase of ceramic micro-particles changed the morphology of (M:Nb,Ta)C with the size from sub-micron to micron. The (M:Nb,Ta)C dispersed along the grain boundary inhibits the growth of the grains. During friction, the spherical structure exhibited a rolling lubrication effect and the petal structure provided a stronger attachment ability to resist the shear. The corrosion occurred at the grains, exhibiting corrosion pits, in which the high content ceramic micro-particles were relatively shallow. Moreover, a few dot corrosion pits were distributed along the grain boundaries without (M:Nb,Ta)C. Therefore, to improve the corrosion resistance, a thin composite carbide coating with good wear and corrosion resistance was prepared.
为提高泵筒材料(40Cr钢)的耐磨和耐蚀性能,采用原位合成复合碳化物的方法制备了(M:Nb,Ta)C/Ni35复合熔覆涂层。系统研究了陶瓷微粒含量对涂层相组成、微观结构、(M:Nb,Ta)C结构特征以及摩擦学和电化学腐蚀行为的影响。陶瓷微粒含量的增加改变了(M:Nb,Ta)C的形态,尺寸从亚微米级变为微米级。沿晶界分布的(M:Nb,Ta)C抑制了晶粒生长。在摩擦过程中,球形结构表现出滚动润滑作用,花瓣状结构具有更强的附着能力以抵抗剪切。腐蚀发生在晶粒处,呈现出腐蚀坑,其中高含量陶瓷微粒的腐蚀坑相对较浅。此外,沿无(M:Nb,Ta)C的晶界分布有一些点蚀坑。因此,为提高耐蚀性,制备了具有良好耐磨和耐蚀性能的薄复合碳化物涂层。