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俄罗斯南乌拉尔地区车里雅宾斯克工业区 PM 和 PM 元素组成及健康风险评估

Elemental Composition of PM and PM and Health Risks Assessment in the Industrial Districts of Chelyabinsk, South Ural Region, Russia.

机构信息

Institute of Natural Sciences and Mathematics, South Ural State University, 454080 Chelyabinsk, Russia.

Ecology & Environment Research Centre, Department of Natural Science, Manchester Metropolitan University, Manchester M1 5GD, UK.

出版信息

Int J Environ Res Public Health. 2021 Nov 24;18(23):12354. doi: 10.3390/ijerph182312354.

Abstract

Air pollution impacts all populations globally, indiscriminately and has site-specific variation and characteristics. Airborne particulate matter (PM) levels were monitored in a typical industrial Russian city, Chelyabinsk in three destinations, one characterized by high traffic volumes and two by industrial zone emissions. The mass concentration and trace metal content of PM and PM were obtained from samples collected during four distinct seasons of 2020. The mean 24-h PM ranged between 6 and 64 μg/m. 24-h PM levels were reported from 5 to 56 μg/m. About half of the 24-h PM and most of the PM values in Chelyabinsk were higher than the WHO recommendations. The mean PM/PM ratio was measured at 0.85, indicative of anthropogenic input. To evaluate the Al, Fe, As, Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn concentration in PM and PM, inductively coupled plasma mass spectrometry (ICP-MS) was used. Fe (337-732 ng/m) was the most abundant component in PM and PM samples while Zn (77-206 ng/m), Mn (10-96 ng/m), and Pb (11-41 ng/m) had the highest concentrations among trace elements. Total non-carcinogenic risks for children were found higher than 1, indicating possible health hazards. This study also presents that the carcinogenic risk for As, Cr, Co, Cd, Ni, and Pb were observed higher than the acceptable limit (1 × 10).

摘要

空气污染对所有国家的所有人群都有影响,且没有差别,其具有特定位置的变化和特征。在俄罗斯一个典型的工业城市车里雅宾斯克的三个地点监测了空气中的颗粒物 (PM) 水平,其中一个地点交通流量大,另外两个地点则有工业区排放。从 2020 年四个不同季节采集的样本中获得了 PM 和 PM 的质量浓度和痕量金属含量。24 小时 PM 的平均值在 6 到 64μg/m 之间。24 小时 PM 水平报告范围在 5 到 56μg/m 之间。车里雅宾斯克约一半的 24 小时 PM 和大部分 PM 值都高于世界卫生组织的建议值。PM/PM 的平均值为 0.85,表明人为输入。为了评估 PM 和 PM 中的 Al、Fe、As、Cd、Co、Cr、Cu、Mn、Ni、Pb 和 Zn 浓度,使用了电感耦合等离子体质谱法 (ICP-MS)。Fe(337-732ng/m)是 PM 和 PM 样品中最丰富的成分,而 Zn(77-206ng/m)、Mn(10-96ng/m)和 Pb(11-41ng/m)在痕量元素中浓度最高。儿童的非致癌总风险大于 1,表明可能存在健康危害。本研究还表明,As、Cr、Co、Cd、Ni 和 Pb 的致癌风险高于可接受限值(1×10)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e879/8657131/309e0d5e1ed6/ijerph-18-12354-g001.jpg

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