Nikulov Alexey
Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, Moscow District, 142432 Chernogolovka, Russia.
Entropy (Basel). 2022 Jan 3;24(1):83. doi: 10.3390/e24010083.
The law of entropy increase postulates the existence of irreversible processes in physics: the total entropy of an isolated system can increase, but cannot decrease. The annihilation of an electric current in normal metal with the generation of Joule heat because of a non-zero resistance is a well-known example of an irreversible process. The persistent current, an undamped electric current observed in a superconductor, annihilates after the transition into the normal state. Therefore, this transition was considered as an irreversible thermodynamic process before 1933. However, if this transition is irreversible, then the Meissner effect discovered in 1933 is experimental evidence of a process reverse to the irreversible process. Belief in the law of entropy increase forced physicists to change their understanding of the superconducting transition, which is considered a phase transition after 1933. This change has resulted to the internal inconsistency of the conventional theory of superconductivity, which is created within the framework of reversible thermodynamics, but predicts Joule heating. The persistent current annihilates after the transition into the normal state with the generation of Joule heat and reappears during the return to the superconducting state according to this theory and contrary to the law of entropy increase. The success of the conventional theory of superconductivity forces us to consider the validity of belief in the law of entropy increase.
孤立系统的总熵可以增加,但不能减少。由于电阻不为零,正常金属中电流湮灭并产生焦耳热,这是一个众所周知的不可逆过程的例子。持续电流是在超导体中观察到的无衰减电流,在转变为正常态后会湮灭。因此,在1933年之前,这种转变被认为是一个不可逆的热力学过程。然而,如果这种转变是不可逆的,那么1933年发现的迈斯纳效应就是与不可逆过程相反过程的实验证据。对熵增定律的坚信迫使物理学家改变了他们对超导转变的理解,1933年之后超导转变被认为是一种相变。这种变化导致了传统超导理论的内部不一致,该理论是在可逆热力学框架内建立的,但却预测了焦耳热。根据该理论,持续电流在转变为正常态并产生焦耳热后会湮灭,而在恢复到超导态时又会重新出现,这与熵增定律相悖。传统超导理论的成功迫使我们思考对熵增定律坚信的有效性。