Optimizing the Properties of Hybrids Based on Graphene Oxide for Carbon Dioxide Capture.

The reduction of CO emissions and its elimination from the atmosphere has become one of the major problems worldwide, since CO is the main cause of the greenhouse effect and climate change. In recent years, a great number of carbonaceous materials that can be used as CO adsorbents have been synthesized. The strategy is usually to synthesize the materials and determine their adsorption capacity without studying previously the factors that influence this capacity. In this work, different properties of the adsorbents are analyzed to study their influence on the CO adsorption capacity. For this purpose, 10 adsorbents have been synthesized using different strategies and characterized with X-ray photoelectron spectroscopy, X-ray diffraction, and micro-Raman spectroscopy. The percentage of sp carbons, the position of the D + D' peak of the second-order Raman spectrum, the micropore volume, and the grain size of the C sp domains have been related to the amount of CO adsorbed by the adsorbents. The results confirm a linear relationship between the volume of the micropores and the CO uptake and it proves that CO retention is favored in those materials that, in addition to having a high volume of micropores, also have low grain size of C.