HPO activation mediated the iron phase transformation and enhanced the removal of bisphenol A on iron carbide-loaded activated biochar.

Zero valent iron-loaded biochar (Fe-BC) has shown promise for the removal of various organic pollutants, but is restricted by reduced specific surface area, low utilization efficiency and limited production of reactive oxygen species (ROS). In this study, iron carbide-loaded activated biochar (FeC-AB) with a high surface area was synthesized through the pyrolysis of HPO activated biochar with Fe(NO), tested for removing bisphenol A (BPA) and elucidated the adsorption and degradation mechanisms. As a result, HPO activated biochar was beneficial for the transformation of Fe to FeC. FeC-AB exhibited a significantly higher removal rate and removal capacity for BPA than that of Fe-BC within a wide pH range of 5.0-11.0, and its performance was maintained even under extremely high salinity and different water sources. Moreover, X-ray photoelectron spectra and density functional theory calculations confirmed that hydrogen bonds were formed between the COOH groups and BPA. O was the major reactive species, constituting 37.0% of the removal efficiency in the degradation of BPA by FeC-AB. Density functional reactivity theory showed that degradation pathway 2 of BPA was preferentially attacked by ROS. Thus, FeC-AB with low cost and excellent recycling performance could be an alternative candidate for the efficient removal of contaminants.