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利用机械应变对石墨烯电极析氢活性进行实时调制。

Real-Time Modulation of Hydrogen Evolution Activity of Graphene Electrodes Using Mechanical Strain.

作者信息

Kim Min A, Sorescu Dan C, Amemiya Shigeru, Jordan Kenneth D, Liu Haitao

机构信息

Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, United States.

National Energy Technology Laboratory, United States Department of Energy, Pittsburgh, Pennsylvania 15236, United States.

出版信息

ACS Appl Mater Interfaces. 2022 Mar 2;14(8):10691-10700. doi: 10.1021/acsami.1c21821. Epub 2022 Feb 16.

Abstract

This paper reports the effect of mechanically applied elastic strain on the hydrogen evolution reaction (HER) activity of graphene under acidic conditions. An applied tensile strain of 0.2% on a graphene electrode is shown to lead to a 1-3% increase in the HER current. The tensile strain increases HER activity, whereas compressive strain decreases it. Density functional theory (DFT) calculations using a periodic graphene slab model predict an increase in the adsorption energy of the H atom with growing tensile strain, consistent with an enhancement of the current density in HER, similar to that observed experimentally.

摘要

本文报道了在酸性条件下机械施加的弹性应变对石墨烯析氢反应(HER)活性的影响。在石墨烯电极上施加0.2%的拉伸应变会使HER电流增加1%-3%。拉伸应变会增加HER活性,而压缩应变则会降低其活性。使用周期性石墨烯平板模型进行的密度泛函理论(DFT)计算预测,随着拉伸应变的增加,H原子的吸附能会增加,这与HER中电流密度的增强一致,与实验观察结果相似。

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