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构建具有异质界面的互穿结构NiCoO/HCNT复合材料作为低厚度微波吸收剂。

Constructing interpenetrating structured NiCoO/HCNT composites with heterogeneous interfaces as low-thickness microwave absorber.

作者信息

Wu Yang, Tian Konghu, Shu Ruiwen, Zhu Jinbo, Liu Yin, Zhang Chao, Huang Yanan, Chen Zhihong

机构信息

School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China.

School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China; Analysis and Test Center, Anhui University of Science and Technology, Huainan 232001, China.

出版信息

J Colloid Interface Sci. 2022 Jun 15;616:44-54. doi: 10.1016/j.jcis.2022.02.027. Epub 2022 Feb 8.

Abstract

Low matching thickness, broad effective absorption bandwidth (EAB, RL < -10 dB) and excellent reflection loss (RL) are desirable properties for the advanced microwave absorption materials (MAMs). We synthesized novel interpenetrating structured rod-like nickel cobaltite (NiCoO)/helical carbon nanotubes (HCNT) composites using the facile hydrothermal technique and heat-treatment process. Owing to the optimum structural design and electromagnetic parameter regulation, the NiCoO/HCNT composites displayed outstanding microwave absorption (MA) across regions of low thickness. When the thickness was only 1.35 mm, the optimized RL and EAB reached -55.9 dB and 4.8 GHz (13.2-18.0 GHz), respectively. Furthermore, the EAB was 10 GHz as the corresponding thickness was regulated with 1.35-2.10 mm, covering both X and the Ku bands. Multiple reflection and scattering, natural resonance, eddy current loss, strong conduction loss, interface polarization, cross-poalarization, and dipolar polarization can be considered to improve MA. Our study proposes a simple approach of synthesizing low-thickness MAMs based on NiCoO and HCNT.

摘要

低匹配厚度、宽有效吸收带宽(EAB,反射损耗RL < -10 dB)以及优异的反射损耗(RL)是先进微波吸收材料(MAM)所需的特性。我们采用简便的水热技术和热处理工艺合成了新型互穿结构的棒状钴酸镍(NiCoO)/螺旋碳纳米管(HCNT)复合材料。由于优化的结构设计和电磁参数调控,NiCoO/HCNT复合材料在低厚度区域表现出出色的微波吸收(MA)性能。当厚度仅为1.35 mm时,优化后的RL和EAB分别达到-55.9 dB和4.8 GHz(13.2 - 18.0 GHz)。此外,当相应厚度在1.35 - 2.10 mm之间调节时,EAB为10 GHz,覆盖了X波段和Ku波段。多次反射和散射、自然共振、涡流损耗、强传导损耗、界面极化、交叉极化和偶极极化都可被视为改善微波吸收的因素。我们的研究提出了一种基于NiCoO和HCNT合成低厚度MAM的简单方法。

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