莠去津、毒虫畏、硫丹硫酸盐和氟乐灵在农业工业废弃物和堆肥有机废弃物上的吸附/解吸及动力学

Sorption/Desorption and Kinetics of Atrazine, Chlorfenvinphos, Endosulfan Sulfate and Trifluralin on Agro-Industrial and Composted Organic Wastes.

作者信息

Rojas Raquel, Repetto Guillermo, Morillo José, Usero José

机构信息

Area of Toxicology, Department of Molecular Biology and Biochemical Engineering, Universidad Pablo de Olavide, Ctra. de Utrera Km. 1, 41013 Seville, Spain.

Department of Chemical and Environmental Engineering, University of Seville, Camino de los Descubrimientos s/n, 41092 Seville, Spain.

出版信息

Toxics. 2022 Feb 14;10(2):85. doi: 10.3390/toxics10020085.

Abstract

The use of pesticides presents a risk to terrestrial and aquatic ecosystems. For this reason, the development of strategies to prevent and restore pollution is of the greatest interest, including the adsorption to organic matter. The aim of the present study was to investigate the sorption/desorption and kinetics of atrazine, chlorfenvinphos, endosulfan sulfate, and trifluralin onto several raw organic wastes by batch experiments. Three kinetic models were used to fit the obtained sorption kinetics data and two to fit the obtained adsorption isotherm data; both the Freundlich and pseudo-second-order kinetic models described the sorption isotherms well. The desorption study revealed hysteresis in all cases, showing strong, and not completely reversible, adsorption in most cases, with the exception of atrazine-sawdust and chlorfenvinphos-sawdust and chicken manure combinations, for which responses were weak and irreversible. The best kinetic, adsorption and desorption constants were achieved for the hydrophobic pesticides. With respect to sorption-desorption rates, orujillo was found to be the best adsorbent for atrazine, while composted urban solid waste was more suitable for trifluralin and endosulfan sulfate. Sorption constants and simple correlations indicated that, not only the organic matter content, but also the nature of the organic matter itself, and the pesticide and adsorbent properties, determine pesticide sorption-desorption. The use of wastes as efficient and cheap adsorbents for reducing the risk of pesticide pollution is proposed.

摘要

农药的使用对陆地和水生生态系统构成风险。因此,制定预防和恢复污染的策略备受关注,包括对有机物的吸附。本研究的目的是通过批量实验研究阿特拉津、毒虫畏、硫丹硫酸盐和氟乐灵在几种原始有机废物上的吸附/解吸及动力学。使用三种动力学模型拟合所得的吸附动力学数据,两种模型拟合所得的吸附等温线数据;Freundlich模型和伪二级动力学模型都能很好地描述吸附等温线。解吸研究表明在所有情况下都存在滞后现象,在大多数情况下显示出强烈且并非完全可逆的吸附,阿特拉津 - 锯末、毒虫畏 - 锯末和鸡粪组合除外,其吸附作用较弱且不可逆。疏水性农药获得了最佳的动力学、吸附和解吸常数。关于吸附 - 解吸速率,发现奥鲁希洛是阿特拉津的最佳吸附剂,而堆肥后的城市固体废物更适合氟乐灵和硫丹硫酸盐。吸附常数和简单的相关性表明,不仅有机物含量,而且有机物本身的性质以及农药和吸附剂的特性,都决定了农药的吸附 - 解吸。建议将这些废物用作高效且廉价的吸附剂以降低农药污染风险。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/350c/8877077/97374a290a9c/toxics-10-00085-g001.jpg

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