Experimental Study on Microstructure and Erosion Mechanisms of Solid Waste Cemented Paste Backfill under the Combined Action of Dry-Wet Cycles and Sulphate Erosion.

Solid waste cemented paste backfill (SWCPB) meets the needs of coal mining area management. SWCPB is a cementitious paste backfill material without added cement and is made only from oil shale residue (OSR), steel slag (SS), soda residue (SR) and water. In this study, mine water characteristics were simulated by combining dry-wet cycling experiments with sulphate erosion experiments. SWCPB was assessed regarding appearance, mass loss, and unconfined compressive strength (UCS), and the erosion products were microscopically analysed with X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The mechanism for erosion of the SWCPB by sulphate-rich mine water was comprehensively analysed and revealed. Research showed that the erosion mechanism was divided into two parts: chemical and physical erosion. Low concentrations of sodium sulphate promoted hydration, thereby contributing to the increased mass and strength of SWCPB. At high sodium sulphate concentrations, the erosion mainly consumed Ca(OH) within the material, and the main generated erosion products were gypsum and ettringite (AFt). This was accompanied by the destructive effects of NaSO crystal expansion, which resulted in damage and the reduced workability of the SWCPB. The whole erosion process was continuous, mainly due to transformations of pits, pores and cracks. The conclusions of this study may provide appropriate guidance for application of SWCPB materials in the treatment of coal mine backfills. In addition, the corresponding theoretical analysis of the erosion mechanism for SWCPB materials is provided.