Graduate School of Regional Innovation Studies, Mie University, 1577 Kurimamachiya-cho, Tsu, 514-8507, Japan.
Department of Environmental and Preventive Medicine, Jichi Medical University School of Medicine, 3311-1 Yakushiji, Shimotsuke, 329-0498, Japan.
Int Arch Occup Environ Health. 2022 Sep;95(7):1557-1565. doi: 10.1007/s00420-022-01840-0. Epub 2022 Feb 25.
Carbon fibers are used in a variety of industrial applications, based on their lightweight and high stiffness properties. There is little information on the characteristics and exposure levels of debris generated during the factory processing of carbon fibers or their composites. This study revisits the general assumption that carbon fibers or their debris released during composite processing are considered safe for human health.
The present interventional study was conducted at a factory located in Japan, and involved on-site collection of debris generated during the industrial processing of polyacrylonitrile (PAN)-based carbon-fiber-reinforced plastic (CFRP). The debris were collected before being exhausted locally from around different factory machines and examined morphologically and quantitatively by scanning electron microscopy. The levels of exposure to respirable carbon fibers at different areas of the factory were also quantified.
The collected debris mainly contained the original carbon fibers broken transversely at the fiber's major axis. However, carbon fiber fragments morphologically compatible with the WHO definition of respirable fibers (length: > 5 μm, width: < 3 μm, length/width ratio: > 3:1) were also found. The concentrations of respirable fibers at the six examined factory areas under standard working conditions in the same factory were below the standard limit of 10 fibers/L, specified for asbestos dust-generating facilities under the Air Pollution Control Law in Japan.
Our study identified potentially dangerous respirable fibers with high aspect ratio, which was generated during the processing of PAN-based CFRP. Regular risk assessment of carbon fiber debris is necessary to ensure work environment safety.
碳纤维具有重量轻、刚性高的特点,因此被广泛应用于各种工业领域。然而,关于碳纤维及其复合材料在工厂加工过程中产生的碎片的特性和暴露水平的信息却很少。本研究重新审视了这样一个普遍假设,即在复合材料加工过程中释放的碳纤维或其碎片被认为对人类健康是安全的。
本研究为一项在日本的工厂进行的干预性研究,涉及在工业加工聚丙烯腈(PAN)基碳纤维增强塑料(CFRP)的过程中现场收集碎片。在这些碎片从工厂不同机器周围局部排放之前进行收集,并用扫描电子显微镜对其进行形态和定量检查。还对工厂不同区域的可吸入碳纤维暴露水平进行了量化。
收集到的碎片主要包含沿纤维主轴横向断裂的原始碳纤维。然而,也发现了与世界卫生组织(WHO)定义的可吸入纤维形态相符的碳纤维碎片(长度:>5μm,宽度:<3μm,长度/宽度比:>3:1)。在同一工厂标准工作条件下,在六个检查的工厂区域中,可吸入纤维的浓度均低于日本《大气污染控制法》规定的用于产生石棉粉尘的设施的 10 纤维/L 标准限值。
我们的研究发现了在 PAN 基 CFRP 加工过程中产生的具有高纵横比的潜在危险的可吸入纤维。需要定期对碳纤维碎片进行风险评估,以确保工作环境的安全。