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海洋环境中微塑料聚合物潜在危害的分级。

Ranking of potential hazards from microplastics polymers in the marine environment.

机构信息

UCD School of Biosystems and Food Engineering, University College Dublin, Belfield Dublin 4, Ireland.

出版信息

J Hazard Mater. 2022 May 5;429:128399. doi: 10.1016/j.jhazmat.2022.128399. Epub 2022 Feb 1.

Abstract

Microplastics (MPs) have been detected globally in the marine environment. MP polymers of various kinds have different toxicity potentials when decomposed into monomers. Also, the toxicity of MPs is influenced by the particle size distribution of MPs. Based on these parameters, a semi-quantitative risk assessment model has been developed in this study to rank MP polymers of potential health concern emerging from marine exposure pathways. A screening strategy was used to categorize three probability factors and two impact factors and calculate the final risk scores. Four different scenarios were assessed to investigate the influence of risk factors on the model output. The screening strategy prioritised PUR, PVC, PAN, ABS, PMMA, SAN, TPU, UP, PET, PS, and HDPE as the top-ranking polymers of concern (descending order). The sensitivity analysis revealed parameters that influenced the final risk score were hazard score based on monomer classification (RF5 coefficient +0.60)> particle size distribution of MPs (RF4 +0.54)> annual global waste generation (RF1 +0.52)> status of degradation in the marine environment (RF3 +0.32)> mean density of polymers (RF2 +0.16). The outcome of this study can inform the scientific community and the policymakers for better management of MPs where regulation and guidelines need to be considered.

摘要

微塑料(MPs)已在全球海洋环境中被检测到。MP 的各种聚合物在分解成单体时具有不同的毒性潜力。此外,MP 的毒性还受到 MPs 粒径分布的影响。基于这些参数,本研究开发了一种半定量风险评估模型,以对海洋暴露途径中出现的潜在健康关注的 MP 聚合物进行排名。采用筛选策略对三个概率因素和两个影响因素进行分类,并计算最终的风险评分。评估了四个不同的场景,以研究风险因素对模型输出的影响。筛选策略将 PUR、PVC、PAN、ABS、PMMA、SAN、TPU、UP、PET、PS 和 HDPE 等聚合物列为优先考虑的聚合物(降序排列)。敏感性分析表明,影响最终风险评分的参数是基于单体分类的危害评分(RF5 系数+0.60)> MPs 的粒径分布(RF4+0.54)> 全球年废物产生量(RF1+0.52)> 海洋环境中的降解状态(RF3+0.32)> 聚合物的平均密度(RF2+0.16)。本研究的结果可以为科学界和决策者提供信息,以便更好地管理 MPs,需要考虑法规和指南。

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