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基于碳纳米管的过硫酸盐活化材料用于降解有机污染物:性能、机制和改性研究进展。

Carbon nanotube-based materials for persulfate activation to degrade organic contaminants: Properties, mechanisms and modification insights.

机构信息

College of Environmental Science and Engineering, Hunan University and Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082, PR China.

College of Environmental Science and Engineering, Hunan University and Key Laboratory of Environmental Biology and Pollution Control (Hunan University), Ministry of Education, Changsha 410082, PR China.

出版信息

J Hazard Mater. 2022 Jun 5;431:128536. doi: 10.1016/j.jhazmat.2022.128536. Epub 2022 Feb 24.

Abstract

Removal of harmful organic matters from environment has great environmental significance. Carbon nanotube (CNT) materials and their composites have been demonstrated to possess excellent catalytic activity towards persulfate (PS) activation for the degradation of organic contaminants. Herein, detailed information concerning the function, modification methods and relevant mechanisms of CNT in persulfate-based advanced oxidation processes (PS-AOPs) for organic pollutant elimination has been reviewed. The activation mechanism of PS by CNT might include radical and nonradical pathways and their synergistic effects. The common strategies to improve the stability and catalytic capability of CNT-based materials have also been put forward. Furthermore, their practical application potential compared with other catalysts has been described. Finally, the challenges faced by CNT in practical application are clearly highlighted. This review should be of value in promoting the research of PS activation by CNT-based materials for degradation of organic pollutants and the corresponding practical applications.

摘要

从环境中去除有害有机物具有重要的环境意义。碳纳米管(CNT)材料及其复合材料已被证明对过硫酸盐(PS)的活化具有优异的催化活性,可用于降解有机污染物。本文详细综述了 CNT 在基于过硫酸盐的高级氧化工艺(PS-AOPs)中用于有机污染物消除的功能、修饰方法及相关机制。CNT 活化 PS 的机制可能包括自由基和非自由基途径及其协同作用。还提出了提高 CNT 基材料稳定性和催化能力的常见策略。此外,还描述了它们与其他催化剂相比的实际应用潜力。最后,还明确指出了 CNT 在实际应用中面临的挑战。本综述对于促进 CNT 基材料对有机污染物降解的 PS 活化研究及其相应的实际应用具有重要意义。

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