Diaz-Basantes Milene F, Nacimba-Aguirre David, Conesa Juan A, Fullana Andres
Department of Food Technology, Central University of Ecuador, Quito, Ecuador.
Department of Chemical Engineering, University of Alicante, 03690 Alicante, Spain.
Food Chem. 2022 Aug 15;385:132721. doi: 10.1016/j.foodchem.2022.132721. Epub 2022 Mar 16.
The present study aims to determine the presence of synthetic polymeric microparticles (MPs) in samples of canned tuna. An analysis procedure of these microparticles was developed and tested. Four brands of tuna marketed in Ecuador canned both in water and oil were analysed. A significant presence of MPs was found: 692 ± 120 MPs/100 g of tuna in water and 442 ± 84 MPs/100 g of tuna in oil. Random samples of the liquid covering the tuna fish in the cans showed 6 MPs/mL in the case of water and 5 MPs/mL in the case of oil-containing samples. A total of 90% of the reported particles presented a size range of 1-50 µm. The number of MPs present in canned tuna suggests that the ingredients and inputs of the canning process greatly contribute to micro polymers. The identification of the microparticles using fluorescence and micro-FTIR spectrometry revealed that PET, polystyrene and nylon were the most frequent MPs present in the samples analysed.
本研究旨在确定罐装金枪鱼样本中是否存在合成聚合物微粒(MPs)。开发并测试了这些微粒的分析程序。对在厄瓜多尔销售的四个品牌的金枪鱼进行了分析,这些金枪鱼既有水罐装的,也有油罐装的。结果发现MPs大量存在:水罐装金枪鱼中每100克有692±120个MPs,油罐装金枪鱼中每100克有442±84个MPs。罐装金枪鱼表面液体的随机样本显示,水罐装的每毫升有6个MPs,含油样本每毫升有5个MPs。报告的颗粒中,共有90%的尺寸范围为1 - 50微米。罐装金枪鱼中MPs的数量表明,罐头加工过程中的成分和投入对微聚合物的形成有很大影响。使用荧光和显微傅里叶变换红外光谱法对微粒进行鉴定发现,聚对苯二甲酸乙二酯(PET)、聚苯乙烯和尼龙是所分析样本中最常见的MPs。