Mi Qi-Xin, Guo Xiao-Chun, Lu Shao-Yong, Deng Yi-Xiang, Lu Hong-Bin, Li Xiang, Liu Xiao-He, Chen Jin-Ming
National Engineering Laboratory for Lake Pollution Control and Ecological Restoration, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
Institute of Water Ecology and Environment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China.
Huan Jing Ke Xue. 2022 Apr 8;43(4):1966-1975. doi: 10.13227/j.hjkx.202108110.
In order to reveal the pollution and risk level of phthalic acid esters (PAEs) in Qiandao Lake, six types of PAEs in 17 sampling points (in Qiandao Lake and its inflowing rivers) in dry and wet seasons were detected. The results showed that six types of PAEs were detected in both dry and wet seasons, with the concentrations of 0.98-5.33 μg·L (average concentration 2.63 μg·L) in the dry season and 3.22-17.88 μg·L (average concentration 7.99 μg·L) in the wet season. In terms of the detection rate and concentration of each monomer PAEs, DiBP, DBP, and DEHP were the main PAEs components in the water body. The measured value of DBP at 10 sampling points and its average mass concentration in the wet season were higher than the national standard (3 μg·L). Principal component analysis indicated that the main sources of PAEs were personal care products, plastics, and domestic waste. The pollution level of PAEs in Qiandao Lake was at a high level at home and abroad. The health risk assessment results in Qiandao Lake showed that the non-carcinogenic risk index of PAEs in the study area was less than 1, which would not produce non-carcinogenic risks to the human body. The carcinogenic risk index of children exceeded 10 at some points, indicating that it may pose carcinogenic risks to children, to which more attention should be paid.
为揭示千岛湖邻苯二甲酸酯类(PAEs)的污染及风险水平,对千岛湖及其入湖河流17个采样点在枯水期和丰水期的6种PAEs进行了检测。结果表明,枯水期和丰水期均检测到6种PAEs,枯水期浓度为0.98 - 5.33 μg·L(平均浓度2.63 μg·L),丰水期为3.22 - 17.88 μg·L(平均浓度7.99 μg·L)。就各单体PAEs的检出率和浓度而言,邻苯二甲酸二丁酯(DiBP)、邻苯二甲酸二丁酯(DBP)和邻苯二甲酸二(2-乙基己基)酯(DEHP)是水体中主要的PAEs成分。10个采样点DBP的测定值及其在丰水期的平均质量浓度高于国家标准(3 μg·L)。主成分分析表明,PAEs的主要来源是个人护理产品、塑料制品和生活垃圾。千岛湖PAEs的污染水平在国内外处于较高水平。千岛湖健康风险评估结果表明,研究区域PAEs的非致癌风险指数小于1,不会对人体产生非致癌风险。部分点位儿童的致癌风险指数超过10,表明可能对儿童构成致癌风险,应予以更多关注。