Suppr超能文献

对H. Zhu、F. Yang、Y. Zhu、A. Li、W. He、J. Huang和G. Li所著的《纳米受限孔隙中水的介电常数研究》的评论,,2020年,,8628

Comment on "investigation of dielectric constants of water in a nano-confined pore" by H. Zhu, F. Yang, Y. Zhu, A. Li, W. He, J. Huang and G. Li, , 2020, , 8628.

作者信息

Mondal Sayantan, Bagchi Biman

机构信息

Solid State and Structural Chemistry Unit, Indian Institute of Science Bengaluru Karnataka India

出版信息

RSC Adv. 2021 Jan 28;11(9):5179-5181. doi: 10.1039/d0ra02726j. eCollection 2021 Jan 25.

Abstract

Zhu recently reported the spatially resolved dielectric profile and value of the average static dielectric constant of water confined inside a silica nanopore. However, the authors neglected the inherent anisotropy and non-local nature of the dielectric response under confinement. Neglect of these important issues produces erroneous results and vastly underestimates the average values. We demonstrate the correct way to incorporate the anisotropy and to obtain the average dielectric constant of cylindrically nanoconfined dipolar fluids. Use of the correct theoretical formalism expectedly shows convergence of the calculated dielectric response to the bulk value with increasing the nanopore size. On the contrary, the equation used by Zhu fails to exhibit the convergence of the same. Instead, decreases as the nanopore size is gradually increased.

摘要

朱最近报道了限制在二氧化硅纳米孔内的水的空间分辨介电分布和平均静态介电常数的值。然而,作者忽略了受限条件下介电响应固有的各向异性和非局部性质。忽略这些重要问题会产生错误结果,并极大地低估平均值。我们展示了纳入各向异性并获得圆柱形纳米受限偶极流体平均介电常数的正确方法。使用正确的理论形式可以预期,随着纳米孔尺寸的增加,计算出的介电响应会收敛到体相值。相反,朱所使用的方程未能表现出同样的收敛性。反而随着纳米孔尺寸逐渐增加而减小。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e67/8694647/e667939af3d9/d0ra02726j-f1.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验