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采用等离子转移弧技术在Inconel-718上对FeCoCrNiMn颗粒进行表面合金化:微观结构与磨损特性

Surface alloying of FeCoCrNiMn particles on Inconel-718 using plasma-transferred arc technique: microstructure and wear characteristics.

作者信息

Jeyaprakash N, Yang Che-Hua, Prabu G, Balamurugan K Ganesa

机构信息

Graduate Institute of Manufacturing Technology, National Taipei University of Technology Taipei 10608 Taiwan Republic of China

Additive Manufacturing Center for Mass Customization Production, National Taipei University of Technology Taipei 10608 Taiwan Republic of China.

出版信息

RSC Adv. 2021 Aug 20;11(45):28271-28285. doi: 10.1039/d1ra03778a. eCollection 2021 Aug 16.

Abstract

Inconel-718 (IN-718) is a commonly used nickel-based superalloy in various fields, such as gas turbine and power generation applications. However, the lower wear and oxidation resistance hinder their wide usage. In this work, FeCoCrNiMn particles were mechanically ball-milled and preplaced on the IN-718 substrate. Then, the preplaced FeCoCrNiMn particles were scanned by heat source using plasma-transferred arc (PTA) technique. The effect of PTA alloying on the phase changes, microstructure, nanohardness and wear resistance has been investigated. The result showed that the PTA region contained different phases, such as FCC, BCC and intermetallic. No cracks were observed in the PTA alloyed region. Moreover, the porous free structure was viewed in the alloyed region, which revealed that the PTA alloying process was effectively used to perform the alloying process. More hard phases, such as NiFe, CoMn, CrMnNi, MnNi, FeCo, FeMn and MnCo, were formed on the PTA-alloyed region. The obtained wear rate of the substrate specimen at 30 N applied load is 2.45 × 10 mm m and 1.79 × 10 mm m for the PTA specimen. Similarly, the wear rate of the substrate specimen at 50 N is 5.38 × 10 mm m and for the PTA sample, it is 2.29 × 10 mm m. The PTA specimen showed lower CoF than the substrate specimen due to increased surface hardness and minimum deformation of asperities. The primary wear type was mildly abrasive, accompanied by slight oxidative wear. Oxygen reacted with the surface alloying elements and formed different oxides, such as CoO, CrO, MnO, MnO, MnO, FeO and FeO. These dense oxidation films covered the working surface and enhanced the wear resistance. The worn-out PTA surface showed that the wear scar depths were shallow and lower than the substrate, and reduced the roughness.

摘要

因科镍合金718(IN - 718)是一种在燃气轮机和发电应用等各个领域常用的镍基高温合金。然而,其较低的耐磨性和抗氧化性阻碍了它们的广泛应用。在这项工作中,对FeCoCrNiMn颗粒进行机械球磨并预先放置在IN - 718基体上。然后,使用等离子转移弧(PTA)技术通过热源对预先放置的FeCoCrNiMn颗粒进行扫描。研究了PTA合金化对相变、微观结构、纳米硬度和耐磨性的影响。结果表明,PTA区域包含不同的相,如面心立方(FCC)、体心立方(BCC)和金属间化合物。在PTA合金化区域未观察到裂纹。此外,在合金化区域观察到多孔自由结构,这表明PTA合金化工艺有效地用于进行合金化过程。在PTA合金化区域形成了更多的硬质相,如NiFe、CoMn、CrMnNi、MnNi、FeCo、FeMn和MnCo。在30 N的加载力下,基体试样的磨损率为2.45×10⁻⁶mm³/m,PTA试样的磨损率为1.79×10⁻⁶mm³/m。同样,在50 N时,基体试样的磨损率为5.38×10⁻⁶mm³/m,PTA试样的磨损率为2.29×10⁻⁶mm³/m。由于表面硬度增加和微凸体变形最小,PTA试样的摩擦系数低于基体试样。主要磨损类型为轻度磨粒磨损,伴有轻微的氧化磨损。氧与表面合金元素反应形成不同的氧化物,如CoO、CrO、MnO₂、MnO₃、MnO₄、FeO和Fe₂O₃。这些致密的氧化膜覆盖在工作表面并提高了耐磨性。磨损后的PTA表面显示磨损疤痕深度较浅且低于基体,并降低了粗糙度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd80/9038031/58e2a978e76d/d1ra03778a-f1.jpg

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