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岩浆脱气在硫化物熔体流动性和金属富集过程中的关键作用。

The critical role of magma degassing in sulphide melt mobility and metal enrichment.

作者信息

Iacono-Marziano Giada, Le Vaillant Margaux, Godel Belinda M, Barnes Stephen J, Arbaret Laurent

机构信息

ISTO, UMR 7327, CNRS, Université d'Orléans, BRGM, F-45071, Orléans, France.

CSIRO, Mineral Resources, Kensington, WA, 6151, Australia.

出版信息

Nat Commun. 2022 Apr 29;13(1):2359. doi: 10.1038/s41467-022-30107-y.

Abstract

Much of the world's supply of battery metals and platinum group elements (PGE) comes from sulphide ore bodies formed in ancient sub-volcanic magma plumbing systems. Research on magmatic sulphide ore genesis mainly focuses on sulphide melt-silicate melt equilibria. However, over the past few years, increasing evidence of the role of volatiles in magmatic sulphide ore systems has come to light. High temperature-high pressure experiments presented here reveal how the association between sulphide melt and a fluid phase may facilitate the coalescence of sulphide droplets and upgrade the metal content of the sulphide melt. We propose that the occurrence of a fluid phase in the magma can favour both accumulation and metal enrichment of a sulphide melt segregated from this magma, independent of the process producing the fluid phase. Here we show how sulphide-fluid associations preserved in the world-class Noril'sk-Talnakh ore deposits, in Polar Siberia, record the processes demonstrated experimentally.

摘要

世界上大部分的电池金属和铂族元素(PGE)供应来自于古代次火山岩浆管道系统中形成的硫化物矿体。岩浆硫化物矿床成因的研究主要集中在硫化物熔体与硅酸盐熔体的平衡上。然而,在过去几年里,越来越多的证据表明挥发物在岩浆硫化物矿床系统中发挥着作用。本文所展示的高温高压实验揭示了硫化物熔体与流体相之间的关联如何促进硫化物液滴的聚结,并提高硫化物熔体中的金属含量。我们提出,岩浆中流体相的出现有利于从该岩浆中分离出的硫化物熔体的聚集和金属富集,而与产生流体相的过程无关。在这里,我们展示了在西伯利亚极地世界级的诺里尔斯克-塔尔纳赫矿床中保存的硫化物与流体的关联如何记录了实验所证明的过程。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/9054852/c1ac0dca24b5/41467_2022_30107_Fig1_HTML.jpg

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