吡咯并稠合茚并芴扩展四硫富瓦烯二聚体——大型多氧化还原体系
Dimers of pyrrolo-annelated indenofluorene-extended tetrathiafulvalenes - large multiredox systems.
作者信息
Broløs Line, Nielsen Mogens Brøndsted
机构信息
Department of Chemistry, University of Copenhagen, Universitetsparken 5 DK-2100 Copenhagen Ø Denmark
出版信息
RSC Adv. 2020 Apr 16;10(26):15030-15033. doi: 10.1039/d0ra02787a.
Abstract
Novel scaffolds of indenofluorene (IF)-extended tetrathiafulvalenes (TTF) were synthesized starting from a new pyrrolo-annelated IF-TTF monomer. Rigid - and -phenylene linked dimers were obtained -arylation reactions of the monomer, and their optical and redox properties were elucidated by UV-Vis absorption spectroscopy and cyclic and differential pulse voltammetries.
摘要
从一种新的吡咯并稠合茚并芴-四硫富瓦烯（IF-TTF）单体出发，合成了茚并芴（IF）扩展四硫富瓦烯（TTF）的新型支架。通过单体的芳基化反应得到了刚性亚苯基连接的二聚体，并通过紫外-可见吸收光谱、循环伏安法和差分脉冲伏安法对其光学和氧化还原性质进行了阐明。
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