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磁场增强喷射电沉积制备的Ni-P/SiC和Ni-P复合涂层的耐蚀性

Corrosion resistance of Ni-P/SiC and Ni-P composite coatings prepared by magnetic field-enhanced jet electrodeposition.

作者信息

Fu Xiuqing, Wang Feixiang, Chen Xinxin, Lin Jinran, Cao Hongbing

机构信息

College of Engineering, Nanjing Agricultural University Nanjing 210031 P. R. China

Key Laboratory of Intelligence Agricultural Equipment of Jiangsu Province Nanjing 210031 P. R. China.

出版信息

RSC Adv. 2020 Sep 15;10(56):34167-34176. doi: 10.1039/d0ra06735k. eCollection 2020 Sep 10.

Abstract

To extend the working life of 45# steel, Ni-P and Ni-P/SiC composite coatings were prepared on its surface by magnetic field-enhanced jet electrodeposition. This study investigated the effect of magnetic field on the corrosion resistance of Ni-P and Ni-P/SiC composite coatings prepared by conventional jet electrodeposition. The surface and cross-sectional morphologies, microstructure, and composition of the composite coatings were determined by scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), and X-ray diffraction (XRD), respectively. The corrosion resistance was studied using a LEXT4100 laser confocal microscope. The introduction of a stable magnetic field was found to improve the surface morphology of the coatings, increase the growth rate, and reduce the agglomeration of nano-SiC (3 g L, 40 nm) particles, thus significantly improving the corrosion resistance of the coatings. The corrosion potential of the Ni-P coating increased from -0.78 V (0 T) to -0.46 V (0.5 T), and the corrosion current density decreased from 9.56 × 10 A dm (0 T) to 4.31 × 10 A dm (0.5 T). The corrosion potential of the Ni-P/SiC coating increased from -0.59 V (0 T) to -0.28 V (0.5 T), and the corrosion current density decreased from 6.01 × 10 A dm (0 T) to 2.90 × 10 A dm (0.5 T).

摘要

为延长45#钢的使用寿命,采用磁场增强喷射电沉积法在其表面制备了Ni-P和Ni-P/SiC复合涂层。本研究考察了磁场对传统喷射电沉积制备的Ni-P和Ni-P/SiC复合涂层耐蚀性的影响。分别通过扫描电子显微镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)测定了复合涂层的表面和截面形貌、微观结构及成分。使用LEXT4100激光共聚焦显微镜研究了涂层的耐蚀性。结果发现,引入稳定磁场可改善涂层的表面形貌,提高生长速率,并减少纳米SiC(3 g/L,40 nm)颗粒的团聚,从而显著提高涂层的耐蚀性。Ni-P涂层的腐蚀电位从-0.78 V(0 T)增加到-0.46 V(0.5 T),腐蚀电流密度从9.56×10 A/dm²(0 T)降低到4.31×10 A/dm²(0.5 T)。Ni-P/SiC涂层的腐蚀电位从-0.59 V(0 T)增加到-0.28 V(0.5 T),腐蚀电流密度从6.01×10 A/dm²(0 T)降低到2.90×10 A/dm²(0.5 T)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9c/9056816/b477cbf59619/d0ra06735k-f1.jpg

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