Highly dispersed ruthenium nanoparticles on nitrogen doped carbon toward efficient hydrogen evolution in both alkaline and acidic electrolytes.

Efficient and inexpensive electrocatalysts toward the hydrogen evolution reaction (HER) play an important role in electrochemical water splitting. Herein, we report the synthesis of highly dispersed ruthenium nanoparticles (2.2 ± 0.4 nm) on nitrogen doped carbon (Ru/N-C) by chemical reduction of RuCl on carbon in the presence of polyvinylpyrrolidone in combination with subsequent pyrolysis. Ru/N-C exhibits an excellent overpotential of 13.5 and 18.5 mV at 10 mA cm in 1.0 M KOH and 0.5 M HSO aqueous solution, respectively, much better than and comparable to those of commercial Pt/C (38.0 and 10.0 mV). The exceptional HER activity arises from high surface area of ultrafine Ru nanoparticles and appropriate Ru electronic state tuned by nitrogen dopant. Furthermore, Ru/N-C demonstrates excellent durability in both alkaline and acidic condition relative to commercial Pt/C. We speculate that the nitrogen dopant might have coordinated with Ru and tightly anchored Ru nanoparticles, preventing them from agglomerating.