Ionic-size dependent electroosmotic flow in ion-selective biomimetic nanochannels.

Electrokinetic phenomena, especially electroosmosis in ion-selective environments, play a key role in many systems, from ion-selective nanopores to cellular processes. In this paper, the impact of ionic size on the electroosmotic flow through an ion-selective soft slit nanochannel is analytically studied. Meanwhile, the modified Poisson-Boltzmann and the modified Navier-Stokes equations were used for modeling the electrostatics and the electrohydrodynamics of the problem, respectively, and the derived equations were solved by linearizing method. The results reveal the importance of considering the effect of ionic size in the calculation, as the steric effects, especially at high charge densities of polyelectrolytes (PELs), dramatically alter both the ions arrangement and the electric potential; and amplify the electroosmotic flow. Considering Debye-Huckel parameters of 4 and 10 for the electrolyte layer and the PEL, respectively, we demonstrate that the dimensionless electroosmotic velocity in a soft nanochannel having a dimensionless soft layer thickness of 0.2, from 3.2 by ignoring the steric effect, can reach the value of 6 by considering the steric effect of ν=0.3.