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通过纳米结构氧化锡/ Nafion/ GCE 对双酚 S 的电化学监测:解决环境污染的方法。

Electrochemical monitoring of bisphenol-s through nanostructured tin oxide/Nafion/GCE: A solution to environmental pollution.

机构信息

Department of Chemistry, Government College University, Hyderabad, Sindh, Pakistan.

Department of Chemistry, Shaheed Benazir Bhutto University, Shaheed Benazirabad, 67450, Sindh, Pakistan.

出版信息

Chemosphere. 2022 Sep;303(Pt 3):135170. doi: 10.1016/j.chemosphere.2022.135170. Epub 2022 May 28.

Abstract

Over the past few decades, phenolic compounds have been broadly exploited in the industries to be utilized in several applications including polycarbonate plastic, food containers, epoxy resins, etc. One of the major compounds in phenolics is Bisphenol-S (BPS) which has dominantly replaced Bisphenol-A in several applications. Phenolic compounds are extensively drained into the environment without proper treatment and cause several health hazards. Thus, to tackle this serious problem an electrochemical sensor based on SnO/GCE has been successfully engineered to monitor the low-level concentration of BPS in water samples. The fabrication of SnO nanoparticles (SnO NPs) was confirmed through FTIR, XRD, and TEM to examine the size, crystallinity, internal texture, and functionalities of the prepared material. The fabricated material was exploited as a chemically modified sensor for the determination of BPS in water samples collected from different sources. Under optimal conditions such as scan sweep 100 mV/s, PBS electrolyte pH of 6, potential window (0.3-1.3 V), the proposed sensor manifested an excellent response for BPS. The LOD of the present method for BPS was calculated as 0.007 μM, respectively. Moreover, the stability and selectivity profile of SnO/GCE for BPS in the real matrix was examined to be outstanding.

摘要

在过去的几十年中,酚类化合物在工业中得到了广泛的应用,可用于多种应用,包括聚碳酸酯塑料、食品容器、环氧树脂等。酚类化合物中的一种主要化合物是双酚 S(BPS),它在许多应用中已取代双酚 A 占据主导地位。酚类化合物未经适当处理就大量排放到环境中,会造成多种健康危害。因此,为了解决这个严重的问题,我们成功地设计了一种基于 SnO/GCE 的电化学传感器,用于监测水样中 BPS 的低浓度。通过 FTIR、XRD 和 TEM 确认了 SnO 纳米粒子(SnO NPs)的制备,以检查所制备材料的尺寸、结晶度、内部结构和功能。该材料被用作化学修饰传感器,用于测定来自不同来源的水样中的 BPS。在最佳条件下,如扫描速率为 100 mV/s、PBS 电解质 pH 值为 6、电位窗口(0.3-1.3 V),所提出的传感器对 BPS 表现出优异的响应。该方法对 BPS 的检测限计算为 0.007 μM。此外,还对 SnO/GCE 在实际基质中对 BPS 的稳定性和选择性进行了研究,结果表明其性能非常出色。

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