Huidobro Jennifer, Aramendia Julene, Arana Gorka, Madariaga Juan Manuel
Analytical Chemistry Department, University of the Basque Country (UPV/EHU), Barrio Sarriena s/n, 48980 Leioa, Spain.
ACS Earth Space Chem. 2021 Jun 17;5(6):1333-1342. doi: 10.1021/acsearthspacechem.0c00329. Epub 2021 May 27.
A lunar feldspathic breccia meteorite, the Northwest Africa (NWA) 11273, was analyzed to compensate the lack of scientific data available about its mineralogy and geochemistry. In order to obtain a deeper characterization of the sample, a strategy based on the combination of nondestructive spectroscopic techniques such as X-ray fluorescence and Raman spectroscopy is used. Both techniques are being used in spatial missions by the Perseverance Rover, so their combination in the laboratory is here proposed as an optimal strategy to study the complete mineralogy of the sample. In addition to finding the minerals indicated by the Meteoritical Society (anorthite, olivine, pyroxene, kamacite, and troilite), other minor minerals were identified, such as zircon and ilmenite, which are minerals related to the Moon geology, as well as calcite and sulfate which can be considered products of terrestrial weathering. Finally, secondary minerals related to alteration processes were also found, such as hematite, quartz, and anatase. In this work, the alteration processes that gave rise to the detected secondary minerals have been proposed.
对一块月长石角砾岩陨石——西北非洲(NWA)11273进行了分析,以弥补关于其矿物学和地球化学的现有科学数据的不足。为了更深入地表征该样品,采用了一种基于X射线荧光和拉曼光谱等无损光谱技术相结合的策略。“毅力号”火星车正在太空任务中使用这两种技术,因此在这里建议将它们在实验室中的结合作为研究该样品完整矿物学的最佳策略。除了发现陨石学会指出的矿物(钙长石、橄榄石、辉石、陨铁和陨硫铁)外,还鉴定出了其他次要矿物,如锆石和钛铁矿,它们是与月球地质相关的矿物,还有方解石和硫酸盐,它们可被视为地球风化的产物。最后,还发现了与蚀变过程相关的次生矿物,如赤铁矿、石英和锐钛矿。在这项工作中,提出了产生检测到的次生矿物的蚀变过程。