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研究铝土矿残渣脱碱处理与氧化铝的深度提取。

Research on the Dealkalization Treatment of Bauxite Residue and Deep Extraction of Alumina.

机构信息

Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores of Ministry of Education, Special Metallurgy and Process Engineering Institute, School of Metallurgy, Northeastern University, Shenyang, 110819, China.

出版信息

Bull Environ Contam Toxicol. 2022 Jul;109(1):180-185. doi: 10.1007/s00128-022-03554-y. Epub 2022 Jun 9.

Abstract

Bauxite residue is the bulk solid waste generated by the alumina industry, and the environmental treatment of bauxite residue has always been a focus of attention. In this study, in the high calcium system, the bauxite residue was intensively digestion by the calcification-carbonation method, and the mole ratio of solution, the mass ratio of CaO/SiO of the digestion process were changed, so that the high-efficiency dealkalization of bauxite residue was realized and the aluminum oxide in bauxite residue was deeply extracted. The experimental results showed that the calcification process could achieve the recovery of 17.83% alumina at 260°C, reaction duration of 60 min, liquid-solid ratio = 5:1, the mass ratio of CaO/SiO = 3.5, and 200 g/L NaOH solution. The whole process can recover 49.61% of alumina from bauxite residue, and 94.4% of alkali in bauxite residue can be removed.

摘要

铝土矿渣是氧化铝工业产生的大宗固体废弃物,铝土矿渣的环境处理一直是关注的焦点。在本研究中,在高钙体系中,采用钙化碳化法对铝土矿渣进行强化浸出,改变溶液的摩尔比、浸出过程中 CaO/SiO 的质量比,实现了铝土矿渣的高效脱碱,并深度提取铝土矿渣中的氧化铝。实验结果表明,在 260°C、反应时间 60min、液固比=5:1、CaO/SiO 质量比=3.5、200g/LNaOH 溶液条件下,钙化过程可回收 17.83%的氧化铝。整个过程可从铝土矿渣中回收 49.61%的氧化铝,铝土矿渣中的碱可去除 94.4%。

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