Ren Jun, Liu Birunxuan, Li Hao, Zhang Ji, Zhu Haiyan, Xiao Meilin, Liu Guojian, Luo Shuqiong
Urban Construction and Digital City Teaching Experiment Center, School of Architecture and Planning, Yunnan University, Kunming 650550, China.
School of Civil Engineering, Suzhou University of Science and Technology, Suzhou 215011, China.
Polymers (Basel). 2022 Jun 19;14(12):2497. doi: 10.3390/polym14122497.
In this study, based upon the investigation of its effect on workability and the mechanical property of cementitious materials, the Box-Behnken design was adopted to establish models describing self-healing performance on mechanical properties of cementitious materials with polymethylmethacrylate (PMMA)/epoxy microcapsule in terms of healing rate of peak strength (Y1), the recovery rate of peak strength (Y2), the healing rate of Young's modulus (Y3), the recovery rate of Young's modulus (Y4), the healing rate of peak strain (Y5), and recovery rate of peak strain (Y6). This was performed under the influence of the four factors, including microcapsule size (X1), microcapsule content (X2), pre-loading (X3), and curing age (X4). The results showed the four factors significantly affect the healing rate and recovery rate of the peak strength, Young's modulus, and peak strain, except the healing rate on peak strain. Moreover, the interaction between the factors showed some influence as well. The numerically optimised values of X1, X2, X3, and X4 are 203 nm, 5.59%, 43.56%, and 21 days, respectively, and the self-healing cementitious materials with desirable mechanical characteristics (Y1 63.67%, Y2 145.22%, Y3 40.34%, Y4 132.22%, Y5 27.66%, and Y6 133.84%) with the highest desirability of 0.9050 were obtained. Moreover, the porosity of the specimen confirmed the healing performance of PMMA/epoxy microcapsules in cementitious materials.
在本研究中,基于对聚甲基丙烯酸甲酯(PMMA)/环氧微胶囊对胶凝材料工作性和力学性能影响的研究,采用Box-Behnken设计建立模型,从峰值强度愈合率(Y1)、峰值强度恢复率(Y2)、杨氏模量愈合率(Y3)、杨氏模量恢复率(Y4)、峰值应变愈合率(Y5)和峰值应变恢复率(Y6)方面描述含PMMA/环氧微胶囊的胶凝材料力学性能的自愈合性能。这是在微胶囊尺寸(X1)、微胶囊含量(X2)、预加载(X3)和养护龄期(X4)这四个因素的影响下进行的。结果表明,除峰值应变愈合率外,这四个因素对峰值强度、杨氏模量和峰值应变的愈合率和恢复率有显著影响。此外,各因素之间的相互作用也显示出一定影响。X1、X2、X3和X4的数值优化值分别为203nm、5.59%、43.56%和21天,获得了具有理想力学特性(Y1为63.67%,Y2为145.22%,Y3为40.34%,Y4为132.22%,Y5为27.66%,Y6为133.84%)且综合可取性最高为0.9050的自愈合胶凝材料。此外,试样的孔隙率证实了PMMA/环氧微胶囊在胶凝材料中的愈合性能。