用于β-烷基化二聚醇形成的N，N-二甲基甲酰胺稳定的钌纳米颗粒催化剂 伯醇的格尔伯特反应。
,-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation Guerbet reaction of primary alcohols.
作者信息
Nagata Tatsuki, Okada Kanji, Kondo Ryota, Toyao Takashi, Shimizu Ken-Ichi, Suzuki Takeyuki, Obora Yasushi
机构信息
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials, and Bioengineering, Kansai University Suita Osaka 564-8680 Japan
Institute for Catalysis, Hokkaido University N-21, W-10 Sapporo 001-0021 Japan.
出版信息
RSC Adv. 2022 Jun 6;12(26):16599-16603. doi: 10.1039/d2ra02381d. eCollection 2022 Jun 1.
,-Dimethylformamide-stabilized Ru nanoparticles (NPs) provide a highly efficient catalyst for the Guerbet reaction of primary alcohols. DMF-modified Ru NPs were synthesized, and characterized by transition electron microscopy, and X-ray absorption spectroscopy, X-ray photoelectronspectroscopy, and Fourier-transform infrared spectroscopy. The Ru NP catalyst was highly durable during catalytic reactions under external additive/solvent-free conditions.
N，N-二甲基甲酰胺稳定的钌纳米颗粒（NPs）为伯醇的格尔伯特反应提供了一种高效催化剂。合成了DMF修饰的钌纳米颗粒，并通过透射电子显微镜、X射线吸收光谱、X射线光电子能谱和傅里叶变换红外光谱对其进行了表征。在无外部添加剂/溶剂的条件下，钌纳米颗粒催化剂在催化反应过程中具有高度的耐久性。
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