Liu Sen, Ding Nan, Wu Yanjie, Zi Lu, Wang Yue, Hu Junhua, Xie Tianyu, Zhou Donglei, Bai Xue, Xu Wen, Song Hongwei
College of Physics, Jilin University, Changchun 130012, China.
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, China.
J Phys Chem Lett. 2022 Jul 7;13(26):6057-6063. doi: 10.1021/acs.jpclett.2c01301. Epub 2022 Jun 27.
Organic-inorganic perovskites have attracted great interest for developing wavelength-selective photodetectors. Currently, the spectral response range of narrowband photodetectors is mainly concentrated within the visible light region, lacking near-infrared photodetectors. Here, we present perovskite narrowband near-infrared photodetectors achieved by transverse propagation of light in perovskite waveguide devices for the first time. The response spectra of photodetectors are continuously tuned from 750 to 1000 nm by changing the perovskite component and the position of the incident light with the full width at half-maximum of 25-80 nm. The theoretical and experimental results reveal that the typical perovskite photodetectors serve as an optical waveguide to confine and propagate the light, in which the long wavelength light propagates a longer distance; oppositely, the short wavelength light with the higher loss in devices fails to produce a photoresponse, owing to the wavelength dependent absorption of perovskite. This provides a new concept for designing narrowband photodetectors and will simulate new applications.
有机-无机钙钛矿在开发波长选择性光电探测器方面引起了极大的兴趣。目前,窄带光电探测器的光谱响应范围主要集中在可见光区域,缺乏近红外光电探测器。在此,我们首次展示了通过光在钙钛矿波导器件中的横向传播实现的钙钛矿窄带近红外光电探测器。通过改变钙钛矿组分和入射光的位置,光电探测器的响应光谱在750至1000nm范围内连续调谐,半高宽为25-80nm。理论和实验结果表明,典型的钙钛矿光电探测器用作光波导来限制和传播光,其中长波长光传播的距离更长;相反,由于钙钛矿的波长依赖性吸收,在器件中具有较高损耗的短波长光无法产生光响应。这为设计窄带光电探测器提供了一个新概念,并将推动新的应用。