用于构建高孔隙率铝基金属有机框架的网状化学
Reticular Chemistry for the Construction of Highly Porous Aluminum-Based -Metal-Organic Frameworks.
作者信息
Alezi Dalal, Jia Jiangtao, Bhatt Prashant M, Shkurenko Aleksander, Solovyeva Vera, Chen Zhijie, Belmabkhout Youssef, Eddaoudi Mohamed
机构信息
Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia.
Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 22254, Saudi Arabia.
出版信息
Inorg Chem. 2022 Jul 18;61(28):10661-10666. doi: 10.1021/acs.inorgchem.2c00756. Epub 2022 Jun 30.
Edge-transitive nets are regarded as appropriate blueprints for the practice of reticular chemistry, and in particular, for the rational design and synthesis of functional metal-organic frameworks (MOFs). Among edge-transitive nets, type I edge-transitive nets have unique coordination figures, offering only one edge-transitive target for their associated expressed -cBUs. Here, we report the reticulation of the binodal edge-transitive (6, 6)-c net in MOF chemistry, namely, the deliberate assembly of trinuclear aluminum clusters and 6-connected hexacarboxylate ligands into highly porous -MOFs. Further studies reveal that Al--MOF-1 shows promising attributes as a storage media for oxygen (O) at high-pressure adsorption studies.
边传递网络被视为网状化学实践的合适蓝图，尤其是用于功能金属有机框架（MOF）的合理设计与合成。在边传递网络中，I型边传递网络具有独特的配位构型，其相关的表达-cBUs仅有一个边传递目标。在此，我们报道了MOF化学中双节点边传递(6, 6)-c网络的网状化，即将三核铝簇和六连接六羧酸盐配体有意组装成高度多孔的-MOFs。进一步研究表明，在高压吸附研究中，Al-MOF-1作为氧气（O）的存储介质显示出有前景的特性。
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