Solvent-free preparation of thermoplastic bio-materials from microcrystalline cellulose (MCC) through reactive extrusion.

Cellulose, as a renewable biopolymer, was acknowledged as a promising alternative for petroleum polymer. However, the poor thermoplasticity of cellulose caused a limitation in its full development. Herein, a solvent-free and simple strategy was proposed for the preparation of thermoplastic bio-materials from microcrystalline cellulose (MCC). Kraft lignin (KL) was employed as a plasticizer in this work. It was demonstrated that MCC-based materials with great thermoplasticity and mechanical properties could be successfully prepared by reactive extrusion. The obtained MCC-based material ML8G (with 50 wt% KL adding) possessed great thermostability and thermoplastic properties with an obvious glass transition temperature (T) at 106 °C. In addition, the bending strength, flexural modulus and storage modulus of the MCC-based material were improved to 20.44 MPa, 3139.47 MPa and 5.81 GPa respectively. Furthermore, the obtained MCC-based material exhibited good water stability and biodegradability. The comprehensive results confirmed the feasibility of MCC-based materials plasticized with KL through reactive extrusion. Overall, this work was a promising development in the field of bio-plastic utilization of natural products from a green source.