Si Hanmo, Liu Qingwang, Fan Zhenzhong, Wang Biao, Tong Qilei, Lin Mengqi
Key Laboratory of Enhanced Oil Recovery of Education Ministry, Northeast Petroleum University, Daqing 163318, China.
Nanomaterials (Basel). 2022 Jul 20;12(14):2488. doi: 10.3390/nano12142488.
The problem of offshore oil leakage has wreaked havoc on the environment and people’s health. A simple and environmentally friendly impregnation method combined with marine mussel bionics was used to address this issue. Using the viscosity of polydopamine (PDA), nano- Fe3O4 and WS2 adhered to the framework of the melamine sponge (MS), and then the magnetic sponge was modified with n-octadecanethiol (OTD), and finally the superhydrophobic magnetic melamine sponge (mMS) was prepared. The modified sponge has superhydrophobicity (WCA, 156.8° ± 1.18°), high adsorbability (40~100 g°g−1), recyclability (oil adsorbability remains essentially unchanged after 25 cycles), efficient oil−water separation performance (>98%), and can quickly separate oil on the water’s surface and underwater. Furthermore, the modified sponge exhibits excellent stability and durability under harsh operating conditions such as strong sunlight, strong acid, strong alkali, and high salt, and can control the direction of the sponge’s movement by loading a magnetic field. To summarize, mMS has many potential applications as a new magnetic adsorption material for dealing with complex offshore oil spill events.
近海石油泄漏问题对环境和人类健康造成了严重破坏。采用一种结合海洋贻贝仿生学的简单且环保的浸渍方法来解决这一问题。利用聚多巴胺(PDA)的粘性,将纳米Fe3O4和WS2附着在三聚氰胺海绵(MS)骨架上,然后用正十八烷硫醇(OTD)对磁性海绵进行改性,最终制备出超疏水磁性三聚氰胺海绵(mMS)。改性后的海绵具有超疏水性(水接触角,156.8°±1.18°)、高吸附性(40~100 g°g−1)、可循环性(25次循环后吸油能力基本保持不变)、高效油水分离性能(>98%),并且能够快速分离水面和水下的油污。此外,改性海绵在强光、强酸、强碱和高盐等恶劣操作条件下表现出优异的稳定性和耐久性,通过加载磁场还能控制海绵的移动方向。综上所述,作为一种用于处理复杂近海石油泄漏事件的新型磁性吸附材料,mMS具有许多潜在应用。