State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing, China.
Shale Gas Evaluation and Exploitation Key Laboratory of Sichuan Province, Chengdu, China.
PLoS One. 2022 Aug 12;17(8):e0271024. doi: 10.1371/journal.pone.0271024. eCollection 2022.
Various types of marine-continental transitional facies are present in the gas-bearing shales of the southeastern Sichuan Basin. A review of the different lithological assemblages in these rocks is important for assessing the likely shale gas content and the development of the storage space. This study of the lithological assemblages of the Permian Longtan Formation in the southeastern Sichuan Basin at Well X1 used core observations, optical thin-section observations, Ar-ion polishing, scanning electron microscopy, and nitrogen adsorption tests to compare and analyze storage space types and pore structures in the shale to determine the sedimentary paleoenvironment, petromineralogy, and organic content. The marine-continental transitional facies in the study area were deposited in a warm climate that favored enrichment by organic matter. The kerogen is type II2-III (average vitrinite reflectance 2.66%), which is within the favorable thermal maturity range for the presence of shale gas. The lithology mainly consists of shale, siltstone, and limestone (with bioclasts), as well as a coal seam. The lithological development divides the Longtan Formation into lower (swamp), middle (tidal flat/lagoon), and upper (delta) sub-members. From lower to upper divisions, the lithofacies evolved from silty shale to clay shale and then to shale intercalated with siltstone or calcareous layers. The proportions of intergranular and dissolution pores in the clay minerals decrease gradually from lower to upper sub-members, and pore size sizes also tend to decrease. Relatively large-diameter pores and microfractures occur in the inorganic matter in the lowest sub-member. Quartz and clay are the main constituents of the shale, respectively contributing to the specific surface area and specific pore volume of the reservoir space.
四川盆地东南部长兴组气页岩中发育多种海陆过渡相类型。综述这些岩石的不同岩性组合对评估可能的页岩气含量和储集空间的发育至关重要。本研究通过岩心观察、光薄片观察、Ar 离子抛光、扫描电子显微镜和氮气吸附测试,对川东南 X1 井二叠系龙潭组的岩性组合进行了研究,对比分析了页岩中储集空间类型和孔隙结构,以确定沉积古环境、岩石矿物学和有机碳含量。研究区海陆过渡相沉积于温暖气候,有利于有机质富集。干酪根为Ⅱ2-Ⅲ型(平均镜质体反射率 2.66%),处于页岩气有利的热成熟范围之内。岩性主要为页岩、粉砂岩和灰岩(含生物碎屑),还有煤层。岩性发育将龙潭组分为下(沼泽)、中(潮坪/泻湖)和上(三角洲)三个亚组。从下至上,岩相从粉砂质页岩演变为泥质页岩,再演变为夹有粉砂岩或钙质层的页岩。粘土矿物中粒间孔和溶解孔的比例从上至下逐渐减小,孔径也趋于减小。在下亚组中,无机物质中存在相对较大直径的孔隙和微裂缝。石英和粘土分别是页岩的主要成分,对储集空间的比表面积和比孔容有贡献。