Zhang Ping, Li Peng-Fei, Zhang Hong-Hao, Deng Lu
School of Electrical and Information Engineering, Tianjin University, Tianjin, People's Republic of China.
Nanotechnology. 2022 Sep 7;33(47). doi: 10.1088/1361-6528/ac8aa2.
Triboelectric nanogenerators (TENG) are generally utilized on the grounds that they can catch low-recurrence mechanical energy from various types of movement and convert it into electricity. It has been proved that the adulteration of conductive particles in the triboelectric layer can improve its output performance, but metal nanomaterials have different properties at different scales. In this paper, the triboelectric layer of TENG is a composite film made of silver nanoparticles (AgNPs) with different particle sizes (20 nm, 50 nm, 200 nm and 500 nm) that were dispersed and mixed with two-component liquid silica gel step by step. The open circuit voltage (Voc) and short circuit current (Isc) of the 20 nm component of the AgNPs-dispersed/two-component liquid silica gel TENG(At-TENG) are 102.8 V and 4.42A, which are higher than the result execution of the other components. Smaller size nanoparticles have more number of nanoparticles when the mass fraction is the same. AgNPs form micro-capacitance structures in the insulating polymer layer and enhance the dielectric properties of the composite films through an interfacial polarization mechanism. At-TENG can light up 53 commercial LEDs and power calculators or wristband electronic watches, proving its utility as a self-powered power source. An extensive experiment proves the advantage of small size using comparison and theoretical analysis and provides suggestions for the selection of TENG dopants.
摩擦纳米发电机(TENG)通常因其能够从各种类型的运动中捕获低频机械能并将其转化为电能而被利用。已经证明,在摩擦电层中掺杂导电颗粒可以提高其输出性能,但金属纳米材料在不同尺度下具有不同的特性。在本文中,TENG的摩擦电层是由不同粒径(20nm、50nm、200nm和500nm)的银纳米颗粒(AgNP)制成的复合薄膜,这些银纳米颗粒逐步分散并与双组分液体硅胶混合。AgNP分散/双组分液体硅胶TENG(At-TENG)的20nm组分的开路电压(Voc)和短路电流(Isc)分别为102.8V和4.42A,高于其他组分的实验结果。当质量分数相同时,较小尺寸的纳米颗粒具有更多的纳米颗粒数量。AgNP在绝缘聚合物层中形成微电容结构,并通过界面极化机制增强复合薄膜的介电性能。At-TENG可以点亮53个商用发光二极管以及为计算器或腕带电子手表供电,证明了其作为自供电电源的实用性。一项广泛的实验通过比较和理论分析证明了小尺寸的优势,并为TENG掺杂剂的选择提供了建议。