Evaluating the impact of turbidity, precipitation, and land use on nutrient levels and atrazine concentrations in Illinois surface water as determined by citizen scientists.

The objective of this study was to evaluate the impact of turbidity, precipitation, land use, and five-week variation on nutrient levels and atrazine concentrations across Illinois state. To acquire the greatest number of samples in a cost and time-sensitive manner, data were collected by citizen scientists. Volunteers collected data regarding five water quality metrics: nitrites, nitrates, phosphates, atrazine, and turbidity once per week from April 19 until May 17, 2017. A subset (24 %) of volunteers also collected turbidity measurements. Data regarding precipitation was obtained from the Community Collaborative Rain, Hail and Snow Network (CoCoRaHS), a long-standing grassroots volunteer network of backyard weather observers. Three ordinal regression analyses were performed: one without a blocking effect, a second with week as a blocking effect, and a third with watershed as a blocking effect. In all cases, turbidity was significantly associated with elevated levels of nitrate (Pseudo R-0.48 to 0.94) and phosphate (Pseudo R-0.60 to 0.80), while precipitation was significantly associated with elevated levels of nitrate (Pseudo R-0.25 to 0.35). While analyzing five-week variation, the nitrite and nitrate levels, but not phosphate or atrazine, tended to increase at each site. Further, nitrite and nitrate levels significantly varied between the four land uses - agricultural, urban, suburban, and park. When data were analyzed by the three most well-sampled watersheds, Kankakee, Des Plaines, and Chicago, it was identified that the nutrient levels in the Kankakee and Chicago watersheds were significantly elevated relative to the Des Plaines watershed. Finally, cluster analysis identified that clusters dominated by agricultural land, and to a lesser extent suburban land use, had the most elevated nutrient concentration and the greatest frequency of atrazine hits. Data collected by citizen scientists can provide insight into the geospatial variability of nutrients and agrichemicals and can do so across large geographies.