The forgotten reagent of photoredox catalysis.

Visible light powers an ever-expanding suite of reactions to both make and break chemical bonds under otherwise mild conditions. As a reagent in photochemical synthesis, light is obviously critical for reactivity but rarely optimized other than in light/dark controls. This Frontier Article presents an overview of recent research that investigates the unique ways light may be manipulated, and its unusual interactions with homogeneous transition metal and organic photocatalysts.