Leaching and characterization studies of heavy metals in contaminated soil using sequenced reagents of oxalic acid, citric acid, and a copolymer of maleic and acrylic acid instead of ethylenediaminetetraacetic acid.

In this work, the removal performance of three environmentally friendly reagents, oxalic acid (OA), citric acid (CA), and a copolymer of maleic and acrylic acid (PMAA), on heavy metals in polluted soil was studied at the optimum conditions and compared their sequenced performance. The results showed that the consecutive washing with the individual acids significantly improved the removal percentage of heavy metals in the soil compared to that of EDTA (10.2%, 71.3%, 29.8%, 61.6%, and 52.4% removal for As, Cd, Cu, Pb, and Zn, respectively). The removal of As, Cd, Cu, Pb, and Zn in the sequence of CA-OA was 65.6%, 79%, 59.1%, 64.6%, and 63.5%, respectively. In addition, the organic acids had little influence on the soil physicochemical properties after washing with slight reductions of acidity (pH) and soil organic matter (SOM), which are the major determinants of the usability of washed soils for plant growth. The germination rate of Sorghum bicolor in CA-OA-washed soils reached over 70% on the 7th day. CA-OA-washed soils collectively stand out in using washed soils for plant growth with the following advantages: simultaneous removal of cationic and anionic metals, less harmful impact on soil properties, and successful support for the germination of crops. Based on the findings, we recommend the CA-OA sequence as the best alternative to EDTA with higher metal removal efficiency and germination success.