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超声/H₂O₂/碘化钾组合体系对水中阿莫西林的催化降解。

Catalytic degradation of amoxicillin from water by a combined system of ultrasound/HO/KI.

机构信息

School of Physics and Telecommunication Engineering, Zhoukou Normal University, Zhoukou, People's Republic of China.

出版信息

Environ Technol. 2024 Jan;45(4):695-704. doi: 10.1080/09593330.2022.2120830. Epub 2022 Oct 2.

Abstract

A new combined system of ultrasound (US)/ HO/KI was presented in this study for the degradation of amoxicillin (AMX). Various parameters that influencing the degradation efficiency, such as ultrasonic power, pH value of the solution, concentrations of HO and KI, initial concentration of AMX were investigated. The maximum degradation efficiency of 84.1% in 60 min was obtained under the optimal conditions when the ultrasonic power was 195 W, the solution pH was 3.2, the concentrations of HO and KI were 120 and 2.4 mmol/L, respectively. Results also showed US/HO/KI system possessed better degradation efficiency compared with that by using the systems of US alone, HO, US/HO, US/KI and HO/KI. The degradation reaction of AMX should be a very complex process, and the corresponding degradation pathways may change at different concentrations or under different reaction conditions. The results indicate that the combined system of US/ HO/KI has great potential applications for the treatment of wastewater containing antibiotics with high concentrations.

摘要

本研究提出了一种新的超声(US)/ HO / KI 联合系统,用于降解阿莫西林(AMX)。研究了影响降解效率的各种参数,如超声功率、溶液 pH 值、HO 和 KI 的浓度、AMX 的初始浓度。当超声功率为 195 W、溶液 pH 值为 3.2、HO 和 KI 的浓度分别为 120 和 2.4 mmol/L 时,在最佳条件下,可获得 84.1%的最大降解效率,在 60 min 内完成。结果还表明,与单独使用 US、HO、US/HO、US/KI 和 HO/KI 系统相比,US/HO/KI 系统具有更好的降解效率。AMX 的降解反应应该是一个非常复杂的过程,相应的降解途径可能会在不同的浓度或不同的反应条件下发生变化。结果表明,US/HO/KI 联合系统具有很大的潜力,可用于处理高浓度抗生素废水。

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